Toward improved PVDF-BaTiO3 composite dielectrics: mechanical activation of the filler versus filler content
Само за регистроване кориснике
2023
Аутори
Đoković, VladimirDudić, Duško
Dojčilović, Radovan
Marinković, Filip S.
Pavlović, Vera P.
Pavlović, Vladimir B.
Vlahović, Branislav
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Barium titanate (BT) perovskite particles were surface modified by means of mechanical treatment and used as inorganic component in polyvinylidene fluoride (PVDF) based composites. The changes in electrical properties of the composite films with increasing in filler content were followed by dielectric spectroscopy, breakdown strength and D-E measurements. A comparison of the properties of the composites prepared with untreated and mechanically activated particles revealed that there is a significant difference in their performances at low filler concentrations (<20 wt%). Introduction of the surface modified ceramic particles into PVDF matrix led to an increase of the dielectric constant without affecting significantly the electrical breakdown strength. In contrast, when as received BT particles were used a filler, both dielectric constants and breakdown strengths of the composite films were lower than the corresponding values observed for the pure PVDF. At higher concentrations, howeve...r, the influence of pre-treatment of the filler on the effective electrical properties becomes less significant. The obtained results were discussed in terms of the pronounced crystallization of polar β and γ crystal phases of PVDF in the presence of surface modified BT fillers, which is confirmed by Raman spectroscopy.
Извор:
Physica Scripta, 2023, 98, 11, 115932-Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200017 (Универзитет у Београду, Институт за нуклеарне науке Винча, Београд-Винча) (RS-MESTD-inst-2020-200017)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200162 (Универзитет у Београду, Физички факултет) (RS-MESTD-inst-2020-200162)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200105 (Универзитет у Београду, Машински факултет) (RS-MESTD-inst-2020-200105)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-MESTD-inst-2020-200116)
- US National Science Foundation [DMR-2101041]
- US Department of Energy/National Nuclear Security Administration [NA0003979]
Колекције
Институција/група
VinčaTY - JOUR AU - Đoković, Vladimir AU - Dudić, Duško AU - Dojčilović, Radovan AU - Marinković, Filip S. AU - Pavlović, Vera P. AU - Pavlović, Vladimir B. AU - Vlahović, Branislav PY - 2023 UR - https://vinar.vin.bg.ac.rs/handle/123456789/11656 AB - Barium titanate (BT) perovskite particles were surface modified by means of mechanical treatment and used as inorganic component in polyvinylidene fluoride (PVDF) based composites. The changes in electrical properties of the composite films with increasing in filler content were followed by dielectric spectroscopy, breakdown strength and D-E measurements. A comparison of the properties of the composites prepared with untreated and mechanically activated particles revealed that there is a significant difference in their performances at low filler concentrations (<20 wt%). Introduction of the surface modified ceramic particles into PVDF matrix led to an increase of the dielectric constant without affecting significantly the electrical breakdown strength. In contrast, when as received BT particles were used a filler, both dielectric constants and breakdown strengths of the composite films were lower than the corresponding values observed for the pure PVDF. At higher concentrations, however, the influence of pre-treatment of the filler on the effective electrical properties becomes less significant. The obtained results were discussed in terms of the pronounced crystallization of polar β and γ crystal phases of PVDF in the presence of surface modified BT fillers, which is confirmed by Raman spectroscopy. T2 - Physica Scripta T1 - Toward improved PVDF-BaTiO3 composite dielectrics: mechanical activation of the filler versus filler content VL - 98 IS - 11 SP - 115932 DO - 10.1088/1402-4896/acff4d ER -
@article{ author = "Đoković, Vladimir and Dudić, Duško and Dojčilović, Radovan and Marinković, Filip S. and Pavlović, Vera P. and Pavlović, Vladimir B. and Vlahović, Branislav", year = "2023", abstract = "Barium titanate (BT) perovskite particles were surface modified by means of mechanical treatment and used as inorganic component in polyvinylidene fluoride (PVDF) based composites. The changes in electrical properties of the composite films with increasing in filler content were followed by dielectric spectroscopy, breakdown strength and D-E measurements. A comparison of the properties of the composites prepared with untreated and mechanically activated particles revealed that there is a significant difference in their performances at low filler concentrations (<20 wt%). Introduction of the surface modified ceramic particles into PVDF matrix led to an increase of the dielectric constant without affecting significantly the electrical breakdown strength. In contrast, when as received BT particles were used a filler, both dielectric constants and breakdown strengths of the composite films were lower than the corresponding values observed for the pure PVDF. At higher concentrations, however, the influence of pre-treatment of the filler on the effective electrical properties becomes less significant. The obtained results were discussed in terms of the pronounced crystallization of polar β and γ crystal phases of PVDF in the presence of surface modified BT fillers, which is confirmed by Raman spectroscopy.", journal = "Physica Scripta", title = "Toward improved PVDF-BaTiO3 composite dielectrics: mechanical activation of the filler versus filler content", volume = "98", number = "11", pages = "115932", doi = "10.1088/1402-4896/acff4d" }
Đoković, V., Dudić, D., Dojčilović, R., Marinković, F. S., Pavlović, V. P., Pavlović, V. B.,& Vlahović, B.. (2023). Toward improved PVDF-BaTiO3 composite dielectrics: mechanical activation of the filler versus filler content. in Physica Scripta, 98(11), 115932. https://doi.org/10.1088/1402-4896/acff4d
Đoković V, Dudić D, Dojčilović R, Marinković FS, Pavlović VP, Pavlović VB, Vlahović B. Toward improved PVDF-BaTiO3 composite dielectrics: mechanical activation of the filler versus filler content. in Physica Scripta. 2023;98(11):115932. doi:10.1088/1402-4896/acff4d .
Đoković, Vladimir, Dudić, Duško, Dojčilović, Radovan, Marinković, Filip S., Pavlović, Vera P., Pavlović, Vladimir B., Vlahović, Branislav, "Toward improved PVDF-BaTiO3 composite dielectrics: mechanical activation of the filler versus filler content" in Physica Scripta, 98, no. 11 (2023):115932, https://doi.org/10.1088/1402-4896/acff4d . .