Corrosion of Ceramic-Metal Composites in Artificial Acid Rain
Апстракт
In this work, the basalt deposits site from southern Serbia was used as a matrix for the composite materials. The corrosion behavior of basalt matrix composites with various ratios of commercial stainless steel 316L (5, 10, 15, and 20 wt.%) and bulk basalt produced by sintering in the air (t=1060ºC and τ=60 min) were studied by immersion corrosion technique. The samples were immersed in a solution of artificial acid rain H2SO4:HNO3 = 9:1 at ≈ pH 3 to measure the concentration of released metal ions using inductively coupled plasma-optical emission spectrometry (ICP-OES). The elements Fe, Cr, Mn, and Ni were monitored, while the others were below the limit of quantification. The concentrations of the metal ions in the solution were studied over 15 weeks. The ions release rate from all the sintered samples was found to follow the Weibull cumulative distribution function (CDF). This means that the release rate changes over time and allows us to calculate the characteristic times of ion re...lease. The changes in the samples were monitored by light microscopy (LM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and weight loss. Sintered basalt shows high resistance to corrosion with a characteristic time of about 18 years for Fe and more than 25 years for Cr and Mn. The weight difference between the initial and after 15 weeks of exposure to the solution (sintered basalt) was not observed. On the other hand, the presence of 5 wt.% steel powder in the sintered basalt accelerates the release of metal ions by about six times. When the steel powder content in the composite materials increases, the metal release rate does not change further, but a weight loss is observed. The characteristic times for Fe, Cr, Ni, and Mn in composite materials are about 5 years. These composite materials can be investigated as materials for using in an acid environment.
Кључне речи:
composite materials / basalt / artificial acid rain / corrosion / Weibull distributionИзвор:
MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina, 2023, 73-73Издавач:
- Belgrade : Association of Metallurgical Engineers of Serbia (AMES)
Напомена:
- 5th Metallurgical & Materials Engineering Congress of South-East Europe (MME SEE 2023) : book of abstracts; June 7-10, Trebinje, Bosnia and Herzegovina
Колекције
Институција/група
VinčaTY - CONF AU - Stoiljković, Milovan AU - Pavkov, Vladimir AU - Bakić, Gordana AU - Luković, Aleksa AU - Maksimović, Vesna PY - 2023 UR - https://vinar.vin.bg.ac.rs/handle/123456789/11563 AB - In this work, the basalt deposits site from southern Serbia was used as a matrix for the composite materials. The corrosion behavior of basalt matrix composites with various ratios of commercial stainless steel 316L (5, 10, 15, and 20 wt.%) and bulk basalt produced by sintering in the air (t=1060ºC and τ=60 min) were studied by immersion corrosion technique. The samples were immersed in a solution of artificial acid rain H2SO4:HNO3 = 9:1 at ≈ pH 3 to measure the concentration of released metal ions using inductively coupled plasma-optical emission spectrometry (ICP-OES). The elements Fe, Cr, Mn, and Ni were monitored, while the others were below the limit of quantification. The concentrations of the metal ions in the solution were studied over 15 weeks. The ions release rate from all the sintered samples was found to follow the Weibull cumulative distribution function (CDF). This means that the release rate changes over time and allows us to calculate the characteristic times of ion release. The changes in the samples were monitored by light microscopy (LM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and weight loss. Sintered basalt shows high resistance to corrosion with a characteristic time of about 18 years for Fe and more than 25 years for Cr and Mn. The weight difference between the initial and after 15 weeks of exposure to the solution (sintered basalt) was not observed. On the other hand, the presence of 5 wt.% steel powder in the sintered basalt accelerates the release of metal ions by about six times. When the steel powder content in the composite materials increases, the metal release rate does not change further, but a weight loss is observed. The characteristic times for Fe, Cr, Ni, and Mn in composite materials are about 5 years. These composite materials can be investigated as materials for using in an acid environment. PB - Belgrade : Association of Metallurgical Engineers of Serbia (AMES) C3 - MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina T1 - Corrosion of Ceramic-Metal Composites in Artificial Acid Rain SP - 73 EP - 73 UR - https://hdl.handle.net/21.15107/rcub_vinar_11563 ER -
@conference{ author = "Stoiljković, Milovan and Pavkov, Vladimir and Bakić, Gordana and Luković, Aleksa and Maksimović, Vesna", year = "2023", abstract = "In this work, the basalt deposits site from southern Serbia was used as a matrix for the composite materials. The corrosion behavior of basalt matrix composites with various ratios of commercial stainless steel 316L (5, 10, 15, and 20 wt.%) and bulk basalt produced by sintering in the air (t=1060ºC and τ=60 min) were studied by immersion corrosion technique. The samples were immersed in a solution of artificial acid rain H2SO4:HNO3 = 9:1 at ≈ pH 3 to measure the concentration of released metal ions using inductively coupled plasma-optical emission spectrometry (ICP-OES). The elements Fe, Cr, Mn, and Ni were monitored, while the others were below the limit of quantification. The concentrations of the metal ions in the solution were studied over 15 weeks. The ions release rate from all the sintered samples was found to follow the Weibull cumulative distribution function (CDF). This means that the release rate changes over time and allows us to calculate the characteristic times of ion release. The changes in the samples were monitored by light microscopy (LM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and weight loss. Sintered basalt shows high resistance to corrosion with a characteristic time of about 18 years for Fe and more than 25 years for Cr and Mn. The weight difference between the initial and after 15 weeks of exposure to the solution (sintered basalt) was not observed. On the other hand, the presence of 5 wt.% steel powder in the sintered basalt accelerates the release of metal ions by about six times. When the steel powder content in the composite materials increases, the metal release rate does not change further, but a weight loss is observed. The characteristic times for Fe, Cr, Ni, and Mn in composite materials are about 5 years. These composite materials can be investigated as materials for using in an acid environment.", publisher = "Belgrade : Association of Metallurgical Engineers of Serbia (AMES)", journal = "MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina", title = "Corrosion of Ceramic-Metal Composites in Artificial Acid Rain", pages = "73-73", url = "https://hdl.handle.net/21.15107/rcub_vinar_11563" }
Stoiljković, M., Pavkov, V., Bakić, G., Luković, A.,& Maksimović, V.. (2023). Corrosion of Ceramic-Metal Composites in Artificial Acid Rain. in MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina Belgrade : Association of Metallurgical Engineers of Serbia (AMES)., 73-73. https://hdl.handle.net/21.15107/rcub_vinar_11563
Stoiljković M, Pavkov V, Bakić G, Luković A, Maksimović V. Corrosion of Ceramic-Metal Composites in Artificial Acid Rain. in MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina. 2023;:73-73. https://hdl.handle.net/21.15107/rcub_vinar_11563 .
Stoiljković, Milovan, Pavkov, Vladimir, Bakić, Gordana, Luković, Aleksa, Maksimović, Vesna, "Corrosion of Ceramic-Metal Composites in Artificial Acid Rain" in MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina (2023):73-73, https://hdl.handle.net/21.15107/rcub_vinar_11563 .