Optimisation of the operating parameters of a thermal plasma system for the conversion of waste containing polychlorinated biphenyls by thermodynamic modelling
Само за регистроване кориснике
2023
Аутори
Cvetinović, DejanMilutinović, Nada
Erić, Aleksandar
Škobalj, Predrag D.
Anđelković, Jovana
Bakić, Vukman
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
This paper proposes a mathematical modelling approach to determine the thermodynamic equilibrium of chemical systems in order to optimise the operating parameters of the plasma chemical processes in a lowtemperature thermal plasma pilot reactor with a direct current electric arc for the treatment of hazardous waste containing polychlorinated biphenyls. The model is primarily based on the principles of mass action and minimum Gibbs free energy. The obtained results can serve as a basis for multi-criteria optimisation based on ecological aspects, reduction of energy consumption and the possibility of using the produced synthetic gas for energy recovery in the process. The analysis carried out clearly showed the advantages of using water vapour as a plasma working medium and the appropriate mixing of the organic waste containing polychlorinated biphenyls with used engine oil for enriched syngas production. The presented analysis determines the optimal reactor temperature for an ecological...ly efficient treatment and shows possibilities for energy recovery in the process. The proposed model can also be used for other chemical reactors and for the treatment of other chemical substances
Кључне речи:
Thermodynamic modelling / Waste containing polychlorinated biphenyls / DC thermal plasma / Multi-criteria optimisation / Ecological and economic aspectsИзвор:
Energy Conversion and Management, 2023, 292, 117358-Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200017 (Универзитет у Београду, Институт за нуклеарне науке Винча, Београд-Винча) (RS-MESTD-inst-2020-200017)
Колекције
Институција/група
VinčaTY - JOUR AU - Cvetinović, Dejan AU - Milutinović, Nada AU - Erić, Aleksandar AU - Škobalj, Predrag D. AU - Anđelković, Jovana AU - Bakić, Vukman PY - 2023 UR - https://vinar.vin.bg.ac.rs/handle/123456789/11352 AB - This paper proposes a mathematical modelling approach to determine the thermodynamic equilibrium of chemical systems in order to optimise the operating parameters of the plasma chemical processes in a lowtemperature thermal plasma pilot reactor with a direct current electric arc for the treatment of hazardous waste containing polychlorinated biphenyls. The model is primarily based on the principles of mass action and minimum Gibbs free energy. The obtained results can serve as a basis for multi-criteria optimisation based on ecological aspects, reduction of energy consumption and the possibility of using the produced synthetic gas for energy recovery in the process. The analysis carried out clearly showed the advantages of using water vapour as a plasma working medium and the appropriate mixing of the organic waste containing polychlorinated biphenyls with used engine oil for enriched syngas production. The presented analysis determines the optimal reactor temperature for an ecologically efficient treatment and shows possibilities for energy recovery in the process. The proposed model can also be used for other chemical reactors and for the treatment of other chemical substances T2 - Energy Conversion and Management T1 - Optimisation of the operating parameters of a thermal plasma system for the conversion of waste containing polychlorinated biphenyls by thermodynamic modelling VL - 292 SP - 117358 DO - 10.1016/j.enconman.2023.117358 ER -
@article{ author = "Cvetinović, Dejan and Milutinović, Nada and Erić, Aleksandar and Škobalj, Predrag D. and Anđelković, Jovana and Bakić, Vukman", year = "2023", abstract = "This paper proposes a mathematical modelling approach to determine the thermodynamic equilibrium of chemical systems in order to optimise the operating parameters of the plasma chemical processes in a lowtemperature thermal plasma pilot reactor with a direct current electric arc for the treatment of hazardous waste containing polychlorinated biphenyls. The model is primarily based on the principles of mass action and minimum Gibbs free energy. The obtained results can serve as a basis for multi-criteria optimisation based on ecological aspects, reduction of energy consumption and the possibility of using the produced synthetic gas for energy recovery in the process. The analysis carried out clearly showed the advantages of using water vapour as a plasma working medium and the appropriate mixing of the organic waste containing polychlorinated biphenyls with used engine oil for enriched syngas production. The presented analysis determines the optimal reactor temperature for an ecologically efficient treatment and shows possibilities for energy recovery in the process. The proposed model can also be used for other chemical reactors and for the treatment of other chemical substances", journal = "Energy Conversion and Management", title = "Optimisation of the operating parameters of a thermal plasma system for the conversion of waste containing polychlorinated biphenyls by thermodynamic modelling", volume = "292", pages = "117358", doi = "10.1016/j.enconman.2023.117358" }
Cvetinović, D., Milutinović, N., Erić, A., Škobalj, P. D., Anđelković, J.,& Bakić, V.. (2023). Optimisation of the operating parameters of a thermal plasma system for the conversion of waste containing polychlorinated biphenyls by thermodynamic modelling. in Energy Conversion and Management, 292, 117358. https://doi.org/10.1016/j.enconman.2023.117358
Cvetinović D, Milutinović N, Erić A, Škobalj PD, Anđelković J, Bakić V. Optimisation of the operating parameters of a thermal plasma system for the conversion of waste containing polychlorinated biphenyls by thermodynamic modelling. in Energy Conversion and Management. 2023;292:117358. doi:10.1016/j.enconman.2023.117358 .
Cvetinović, Dejan, Milutinović, Nada, Erić, Aleksandar, Škobalj, Predrag D., Anđelković, Jovana, Bakić, Vukman, "Optimisation of the operating parameters of a thermal plasma system for the conversion of waste containing polychlorinated biphenyls by thermodynamic modelling" in Energy Conversion and Management, 292 (2023):117358, https://doi.org/10.1016/j.enconman.2023.117358 . .