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Heavily doped high-entropy A2B2O7 pyrochlore
dc.creator | Matović, Branko | |
dc.creator | Maletaškić, Jelena | |
dc.creator | Maksimović, Vesna | |
dc.creator | Zagorac, Jelena | |
dc.creator | Luković, Aleksa | |
dc.creator | Zeng, Yu-Ping | |
dc.creator | Cvijović-Alagić, Ivana | |
dc.date.accessioned | 2023-08-04T09:53:08Z | |
dc.date.available | 2023-08-04T09:53:08Z | |
dc.date.issued | 2023 | |
dc.identifier.issn | 1820-6131 | |
dc.identifier.issn | 2406-1034 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/11324 | |
dc.description.abstract | A novel class of high-entropy pyrochlore compounds with multiple elements at the A and B site positions (A2B2O7) was successfully obtained. Powders with (La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 nominal composition were fabricated from pure metal oxides obtained through a reaction of metal nitrates (for site A) and metal chlorides (for site B) with sodium hydroxide during the solid-state displacement reaction (SSDR). The phase evolution was analyzed using XRD method. During the thermal treatment of ten individual metal oxides, the single pyrochlore phase was created. The present study showed that the highdensity (98%TD) ceramics with a hardness of 8.1GPa was successfully obtained after pressureless sintering at 1650 °C for 4 h. Results of the Raman study and the Rietveld structural refinement showed that sintered highentropy ceramics is characterized by a single-phase pyrochlore structure, which was investigated in detail. | en |
dc.language.iso | en | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200017/RS// | |
dc.relation | Visiting Professor Program of the Chinese Academy of Sciences [2021VEA0003] | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | Processing and Application of Ceramics | en |
dc.subject | high-entropy oxide | en |
dc.subject | pyrochlore | en |
dc.subject | phase evolution | en |
dc.subject | XRD | en |
dc.subject | microstructure | en |
dc.subject | hardness | en |
dc.title | Heavily doped high-entropy A2B2O7 pyrochlore | en |
dc.type | article | en |
dc.rights.license | BY | |
dc.citation.volume | 17 | |
dc.citation.issue | 2 | |
dc.citation.spage | 113 | |
dc.citation.epage | 117 | |
dc.identifier.doi | 10.2298/PAC2302113M | |
dc.type.version | publishedVersion | |
dc.identifier.fulltext | http://vinar.vin.bg.ac.rs/bitstream/id/30756/1820-61312302113M.pdf |
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