SiC synthesis using domestic mineral resources
Аутори
Devečerski, AleksandarPošarac, Milica B.
Egelja, Adela
Rosić, Milena
Volkov-Husović, Tatjana
Matović, Branko
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The possibility of using domestic Mg-silicate (sepiolite, white) as Si source and novolac resin (as carbon source), for synthesis of fine β-SiC powder at relatively low temperatures (1673-1873 K), was demonstrated. Obtained SiC powders consist of fine β-SiC particles and did not retain the fibrous morphology of starting sepiolites. Carbothermal reduction process, which was used in this study, is greatly influenced by catalyst addition (FeCl3, FeSi). In order to obtain pure SiC powders, it is necessary to completely remove all Mg-species, and catalytic influence of Fe is attributed to FeSi important role in reduction of Mg2SiO4 and MgO into Mg(g). Formation of SiC whiskers is observed only in samples with Fe introduced in form of iron-silicide (FeSi).
Кључне речи:
SiC / sepiolite / carbothermal reduction / Mg-silicateИзвор:
Processing and Application of Ceramics, 2011, 5, 2, 63-67Финансирање / пројекти:
- Синтеза, процесирање и карактеризација наноструктурних материјала за примену у области енергије, механичког инжењерства, заштите животне стредине и биомедицине (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45012)
Институција/група
VinčaTY - JOUR AU - Devečerski, Aleksandar AU - Pošarac, Milica B. AU - Egelja, Adela AU - Rosić, Milena AU - Volkov-Husović, Tatjana AU - Matović, Branko PY - 2011 UR - https://vinar.vin.bg.ac.rs/handle/123456789/11033 AB - The possibility of using domestic Mg-silicate (sepiolite, white) as Si source and novolac resin (as carbon source), for synthesis of fine β-SiC powder at relatively low temperatures (1673-1873 K), was demonstrated. Obtained SiC powders consist of fine β-SiC particles and did not retain the fibrous morphology of starting sepiolites. Carbothermal reduction process, which was used in this study, is greatly influenced by catalyst addition (FeCl3, FeSi). In order to obtain pure SiC powders, it is necessary to completely remove all Mg-species, and catalytic influence of Fe is attributed to FeSi important role in reduction of Mg2SiO4 and MgO into Mg(g). Formation of SiC whiskers is observed only in samples with Fe introduced in form of iron-silicide (FeSi). T2 - Processing and Application of Ceramics T1 - SiC synthesis using domestic mineral resources VL - 5 IS - 2 SP - 63 EP - 67 DO - 10.2298/PAC1102063D ER -
@article{ author = "Devečerski, Aleksandar and Pošarac, Milica B. and Egelja, Adela and Rosić, Milena and Volkov-Husović, Tatjana and Matović, Branko", year = "2011", abstract = "The possibility of using domestic Mg-silicate (sepiolite, white) as Si source and novolac resin (as carbon source), for synthesis of fine β-SiC powder at relatively low temperatures (1673-1873 K), was demonstrated. Obtained SiC powders consist of fine β-SiC particles and did not retain the fibrous morphology of starting sepiolites. Carbothermal reduction process, which was used in this study, is greatly influenced by catalyst addition (FeCl3, FeSi). In order to obtain pure SiC powders, it is necessary to completely remove all Mg-species, and catalytic influence of Fe is attributed to FeSi important role in reduction of Mg2SiO4 and MgO into Mg(g). Formation of SiC whiskers is observed only in samples with Fe introduced in form of iron-silicide (FeSi).", journal = "Processing and Application of Ceramics", title = "SiC synthesis using domestic mineral resources", volume = "5", number = "2", pages = "63-67", doi = "10.2298/PAC1102063D" }
Devečerski, A., Pošarac, M. B., Egelja, A., Rosić, M., Volkov-Husović, T.,& Matović, B.. (2011). SiC synthesis using domestic mineral resources. in Processing and Application of Ceramics, 5(2), 63-67. https://doi.org/10.2298/PAC1102063D
Devečerski A, Pošarac MB, Egelja A, Rosić M, Volkov-Husović T, Matović B. SiC synthesis using domestic mineral resources. in Processing and Application of Ceramics. 2011;5(2):63-67. doi:10.2298/PAC1102063D .
Devečerski, Aleksandar, Pošarac, Milica B., Egelja, Adela, Rosić, Milena, Volkov-Husović, Tatjana, Matović, Branko, "SiC synthesis using domestic mineral resources" in Processing and Application of Ceramics, 5, no. 2 (2011):63-67, https://doi.org/10.2298/PAC1102063D . .