Biocomoposites of polylactic acid/ poly(butylene adipate-co-terephthalate) blends loaded with quinoa husk agro-waste: thermal and mechanical properties
Само за регистроване кориснике
2022
Аутори
Ponce, GiovanniRodríguez-Llamazares, Saddys
Rivera, Patricia Castaño
Castaño, Johanna
Oporto-Velásquez, Gloria
Sabando, Constanza
Ide, Walter
Nešić, Aleksandra
Cabrera-Barjas, Gustavo
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Quinoa husk (QH) is often discarded without being utilized. This study investigates an alternative route for this agro-waste resource as a raw material in the preparation of bioplastic composites. The effect of QH on the mechanical and thermal properties of thermoplastic poly(lactic acid)/poly(butylene adipate-co-terephthalate) (PLA/PBAT) blends was evaluated. The composites were prepared by melting compounding. The content of quinoa husk in composite materials varied from 0-30 wt%. The results demonstrated that addition of quinoa husk in PLA/PBAT blend induced slight increase in crystalline phase of PLA, which was evidenced by FTIR and DSC analysis. However, it reduced the mechanical and thermal properties of materials. The 30 wt% load of quinoa husk in formulation led to decreased tensile strength (by 45.5%), elongation at break (by 85.8%), thermal stability (by 23.5%) and flexural strength (by 36%) of final biocomposite material, when compared to the control biopolymer blend. Althou...gh addition of quinoa husk in bioplastic material did not improve mechanical properties, load of 20 wt% QH in PLA/PBAT still provided satisfied tensile strength of 19 MPa and flexural strength of 27 MPa, showing that quinoa husk can add value to lignocellulosic by-product/agro waste, particularly decreasing the cost and increasing the sustainability of bioplastic materials for use in the agriculture industry.
Кључне речи:
Mechanical properties / PBAT / PLA / Quinoa husk / Thermal propertiesИзвор:
Journal of Polymer Research, 2022, 29, 8, 356-Финансирање / пројекти:
- CONICYT [Grant PIA/APOYO CCTE AFB170007]
- ANID International Collaboration [Project REDES 190181, CIPA, ANID Regional, GORE BIO BIO, R17A10003, ACE210016, ACE210012, ANID BASAL FB210015 CENAMAD, INNOVA CREA Y VALIDA, 19CVC-118593]
DOI: 10.1007/s10965-022-03196-y
ISSN: 1572-8935
WoS: 00083302340000
Scopus: 2-s2.0-85135155531
Институција/група
VinčaTY - JOUR AU - Ponce, Giovanni AU - Rodríguez-Llamazares, Saddys AU - Rivera, Patricia Castaño AU - Castaño, Johanna AU - Oporto-Velásquez, Gloria AU - Sabando, Constanza AU - Ide, Walter AU - Nešić, Aleksandra AU - Cabrera-Barjas, Gustavo PY - 2022 UR - https://vinar.vin.bg.ac.rs/handle/123456789/10378 AB - Quinoa husk (QH) is often discarded without being utilized. This study investigates an alternative route for this agro-waste resource as a raw material in the preparation of bioplastic composites. The effect of QH on the mechanical and thermal properties of thermoplastic poly(lactic acid)/poly(butylene adipate-co-terephthalate) (PLA/PBAT) blends was evaluated. The composites were prepared by melting compounding. The content of quinoa husk in composite materials varied from 0-30 wt%. The results demonstrated that addition of quinoa husk in PLA/PBAT blend induced slight increase in crystalline phase of PLA, which was evidenced by FTIR and DSC analysis. However, it reduced the mechanical and thermal properties of materials. The 30 wt% load of quinoa husk in formulation led to decreased tensile strength (by 45.5%), elongation at break (by 85.8%), thermal stability (by 23.5%) and flexural strength (by 36%) of final biocomposite material, when compared to the control biopolymer blend. Although addition of quinoa husk in bioplastic material did not improve mechanical properties, load of 20 wt% QH in PLA/PBAT still provided satisfied tensile strength of 19 MPa and flexural strength of 27 MPa, showing that quinoa husk can add value to lignocellulosic by-product/agro waste, particularly decreasing the cost and increasing the sustainability of bioplastic materials for use in the agriculture industry. T2 - Journal of Polymer Research T1 - Biocomoposites of polylactic acid/ poly(butylene adipate-co-terephthalate) blends loaded with quinoa husk agro-waste: thermal and mechanical properties VL - 29 IS - 8 SP - 356 DO - 10.1007/s10965-022-03196-y ER -
@article{ author = "Ponce, Giovanni and Rodríguez-Llamazares, Saddys and Rivera, Patricia Castaño and Castaño, Johanna and Oporto-Velásquez, Gloria and Sabando, Constanza and Ide, Walter and Nešić, Aleksandra and Cabrera-Barjas, Gustavo", year = "2022", abstract = "Quinoa husk (QH) is often discarded without being utilized. This study investigates an alternative route for this agro-waste resource as a raw material in the preparation of bioplastic composites. The effect of QH on the mechanical and thermal properties of thermoplastic poly(lactic acid)/poly(butylene adipate-co-terephthalate) (PLA/PBAT) blends was evaluated. The composites were prepared by melting compounding. The content of quinoa husk in composite materials varied from 0-30 wt%. The results demonstrated that addition of quinoa husk in PLA/PBAT blend induced slight increase in crystalline phase of PLA, which was evidenced by FTIR and DSC analysis. However, it reduced the mechanical and thermal properties of materials. The 30 wt% load of quinoa husk in formulation led to decreased tensile strength (by 45.5%), elongation at break (by 85.8%), thermal stability (by 23.5%) and flexural strength (by 36%) of final biocomposite material, when compared to the control biopolymer blend. Although addition of quinoa husk in bioplastic material did not improve mechanical properties, load of 20 wt% QH in PLA/PBAT still provided satisfied tensile strength of 19 MPa and flexural strength of 27 MPa, showing that quinoa husk can add value to lignocellulosic by-product/agro waste, particularly decreasing the cost and increasing the sustainability of bioplastic materials for use in the agriculture industry.", journal = "Journal of Polymer Research", title = "Biocomoposites of polylactic acid/ poly(butylene adipate-co-terephthalate) blends loaded with quinoa husk agro-waste: thermal and mechanical properties", volume = "29", number = "8", pages = "356", doi = "10.1007/s10965-022-03196-y" }
Ponce, G., Rodríguez-Llamazares, S., Rivera, P. C., Castaño, J., Oporto-Velásquez, G., Sabando, C., Ide, W., Nešić, A.,& Cabrera-Barjas, G.. (2022). Biocomoposites of polylactic acid/ poly(butylene adipate-co-terephthalate) blends loaded with quinoa husk agro-waste: thermal and mechanical properties. in Journal of Polymer Research, 29(8), 356. https://doi.org/10.1007/s10965-022-03196-y
Ponce G, Rodríguez-Llamazares S, Rivera PC, Castaño J, Oporto-Velásquez G, Sabando C, Ide W, Nešić A, Cabrera-Barjas G. Biocomoposites of polylactic acid/ poly(butylene adipate-co-terephthalate) blends loaded with quinoa husk agro-waste: thermal and mechanical properties. in Journal of Polymer Research. 2022;29(8):356. doi:10.1007/s10965-022-03196-y .
Ponce, Giovanni, Rodríguez-Llamazares, Saddys, Rivera, Patricia Castaño, Castaño, Johanna, Oporto-Velásquez, Gloria, Sabando, Constanza, Ide, Walter, Nešić, Aleksandra, Cabrera-Barjas, Gustavo, "Biocomoposites of polylactic acid/ poly(butylene adipate-co-terephthalate) blends loaded with quinoa husk agro-waste: thermal and mechanical properties" in Journal of Polymer Research, 29, no. 8 (2022):356, https://doi.org/10.1007/s10965-022-03196-y . .