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dc.creatorRatkovic, Zoran
dc.creatorMuskinja, Jovana
dc.creatorNovaković, Slađana B.
dc.creatorBogdanović, Goran A.
dc.creatorMicskei, Karoly
dc.creatorVukicevic, Rastko D.
dc.date.accessioned2018-03-01T15:22:22Z
dc.date.available2018-03-01T15:22:22Z
dc.date.issued2014
dc.identifier.issn0277-5387 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/101
dc.description.abstractThe title compound 4-[(dimethylamino)methylene]-2-ferrocenyl-5-oxo-4,5-dihydrofuran-3-carboxaldehyde was synthesized by reacting 3-ferrocenoylpropionic acid with Vilsmeier reagent. This result is rather unexpected, since 3-aroylpropanoic acids under these conditions usually give the corresponding 2-aryl-4-chloro-3-formylfurans. 3-Ferrocenoylpropanoic acid is not the only 3-aroylpropanoic acid that exhibit an unusual behavior under the same conditions: 3-thenoylpropanoic acid gave 4-[(dimethylamino)-methylene]-2-(2-thienyl)-5-oxo-4,5-dihydrofuran-3-carboxaldehyde and 4-[(dimethylamino) methylene]-2-(2-thienyl-5-formyl)-5-oxo-4,5-dihydrofuran-3-carboxaldehyde, whereas 3-(4-methoxybenzoyl)propanoic acid yielded 4-[(dimethylamino)methylene]-2-(4-methoxyphenyl)-5-oxo-4,5-dihydrofuran-3-carboxaldehyde and 2-(4-methoxyphenyl)-5-chloro-furan-3,4-dicarboxaldehyde. Single crystal X-ray analysis was successfully performed for 4-[(dimethylamino)methylene]-2-ferrocenyl-5-oxo-4,5-dihydrofuran-3-carboxaldehyde and 4-[(dimethylamino)methylene]-2-(2-thienyl)-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde and their structures were compared. (C) 2014 Elsevier Ltd. All rights reserved.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172034/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172014/RS//
dc.rightsrestrictedAccessen
dc.sourcePolyhedronen
dc.subject3-Aroylpropanoic acidsen
dc.subject3-Ferocenoylpropanoic aciden
dc.subjectVilsmeier reagenten
dc.subjectFuran derivativesen
dc.subjectCrystal structureen
dc.title4-[(Dimethylamino)methylene]-2-ferrocenyl-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde: Synthesis, spectral characterization and single crystal X-ray analysisen
dc.typearticleen
dcterms.abstractНоваковић Слађана; Мускиња, Јована; Ратковиц, Зоран; Вукицевиц, Растко Д.; Мицскеи, Каролy; Богдановић Горан;
dc.citation.volume80
dc.citation.issueSI
dc.citation.spage193
dc.citation.epage197
dc.identifier.wos000341348300025
dc.identifier.doi10.1016/j.poly.2014.03.038
dc.citation.otherSpecial Issue: SI
dc.citation.rankM22
dc.identifier.scopus2-s2.0-84905442719


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