Nišić, Neda

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  • Nišić, Neda (15)

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Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry

Stojmenović, Marija; Gulicovski, Jelena; Nišić, Neda; Ristić, Nenad; Liu, Shanke; Loredo, Jorge; Kragović, Milan

(2024)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Gulicovski, Jelena
AU  - Nišić, Neda
AU  - Ristić, Nenad
AU  - Liu, Shanke
AU  - Loredo, Jorge
AU  - Kragović, Milan
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12916
AB  - This research presented, for the first time, the results of the successful application of the waste press sludges, WSLP (plant for lacquer and paint) and WSEP (powdery enamel plant), from a wastewater treatment plant generated during heating device production in the construction industry. The results of WSEP characterization and its influence on cement paste, mortar, and concrete properties showed that this material could be used as a cement replacement (with a maximum replacement amount of 20%) in producing mortar and concrete. Although waste WSLP sludge does not possess pozzolanic properties and does not meet the criteria prescribed by the standards for application in mortar and concrete due to its chemical inertness and fineness, as well as its extended setting time, it can be used as a replacement for stone filler or other powdered mineral admixture in the production of self-compacting concrete (SCC) in amounts up to 100%, with a maximum quantity of up to 100 kg/m3. The obtained results indicate that with the appropriate conversion, waste sludges, despite representing hazardous waste, can be used as safe products in the construction industry; i.e., the waste material can become a useful and valuable raw material by applying (respecting) all of the principles of the green economy.
T2  - Materials
T1  - Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry
VL  - 17
IS  - 5
SP  - 1089
DO  - 10.3390/ma17051089
ER  - 
@article{
author = "Stojmenović, Marija and Gulicovski, Jelena and Nišić, Neda and Ristić, Nenad and Liu, Shanke and Loredo, Jorge and Kragović, Milan",
year = "2024",
abstract = "This research presented, for the first time, the results of the successful application of the waste press sludges, WSLP (plant for lacquer and paint) and WSEP (powdery enamel plant), from a wastewater treatment plant generated during heating device production in the construction industry. The results of WSEP characterization and its influence on cement paste, mortar, and concrete properties showed that this material could be used as a cement replacement (with a maximum replacement amount of 20%) in producing mortar and concrete. Although waste WSLP sludge does not possess pozzolanic properties and does not meet the criteria prescribed by the standards for application in mortar and concrete due to its chemical inertness and fineness, as well as its extended setting time, it can be used as a replacement for stone filler or other powdered mineral admixture in the production of self-compacting concrete (SCC) in amounts up to 100%, with a maximum quantity of up to 100 kg/m3. The obtained results indicate that with the appropriate conversion, waste sludges, despite representing hazardous waste, can be used as safe products in the construction industry; i.e., the waste material can become a useful and valuable raw material by applying (respecting) all of the principles of the green economy.",
journal = "Materials",
title = "Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry",
volume = "17",
number = "5",
pages = "1089",
doi = "10.3390/ma17051089"
}
Stojmenović, M., Gulicovski, J., Nišić, N., Ristić, N., Liu, S., Loredo, J.,& Kragović, M.. (2024). Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry. in Materials, 17(5), 1089.
https://doi.org/10.3390/ma17051089
Stojmenović M, Gulicovski J, Nišić N, Ristić N, Liu S, Loredo J, Kragović M. Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry. in Materials. 2024;17(5):1089.
doi:10.3390/ma17051089 .
Stojmenović, Marija, Gulicovski, Jelena, Nišić, Neda, Ristić, Nenad, Liu, Shanke, Loredo, Jorge, Kragović, Milan, "Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry" in Materials, 17, no. 5 (2024):1089,
https://doi.org/10.3390/ma17051089 . .
1

Zakonska regulativa u upravljanju čvrstim industrijskim otpadom u Srbiji - izazovi na putu razvoja cirkularne ekonomije

Nišić, Dragana; Pantelić, Uroš; Nišić, Neda

(2024)

TY  - JOUR
AU  - Nišić, Dragana
AU  - Pantelić, Uroš
AU  - Nišić, Neda
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12954
AB  - Upravljanje čvrstim industrijskim otpadom je regulisan kroz nekoliko zakonskih akata u Srbiji i trenutno se aktivno radi na unapređenju zakonskih normi koje regulišu prevođenje otpada u materije koje nisu otpad, kako bi se ostvarili ciljevi postavljeni Zelenom agendom i Nacionalnim planom upravljanja otpadom. U ovom radu dat je pregled zakonskih propisa kojim se uređuje upravljanje ot-padom, sa posebnim osvrtom na akte i članove akata koji regulišu ponovnu upotrebu čvrstog industrijskog otpada. Navedene su moguće prepreke i nedoumice koje se mogu javiti prilikom tumačenja zakonskih odredbi sa fokusom na sličnostima i razlikama u smernicama za prevođenje otpada u nusproizvod i materiju koja je izgubila status otpada, mogućnosti ponovnog iskorišćenja opasnog otpada i specifičnosti uvoza otpada koji više nije otpad u Srbiju iz neke od zemalja Evropske unije. Kroz konkretan primer prevođenja letećeg pepela u korisnu cementu sirovinu ilustrovane su neke poteškoće na koje se nailazilo do sada u praksi. U zaključku ovog rada predložene su određene mere, kojima bi se navedene prepreke u implementaciji cirkularne ekonomije kroz podsticaj ponovnog iskorišćenja industrijskog otpada, prevazišle.
AB  - The management of industrial solid waste is regulated through several legal acts in Serbia, and in the last few years intensive work has been done to improve the legal norms that regulate the conversion of waste into materials that are no longer waste, in order to achieve the goals, set by the Green Agenda and the National Waste Management Plan. This paper provides an overview of the legal regulations which are regulating waste management, with special reference to acts and articles of acts that regulate the reuse and recovery of solid industrial waste. Possible obstacles and doubts that may arise when interpreting legal provisions are listed, with a focus on similarities and differences in the guidelines for converting waste into a by-product and material with and of waste status, the possibility of hazardous waste recovery, and the specifics of importing waste that is no longer waste into Serbia from one of the countries of the European Union. Through an example of converting fly ash into a useful cementitious raw material, some difficulties that have been encountered so far in practice are illustrated. In the conclusion of this paper, certain measures were proposed to overcome the mentioned obstacles in the implementation of the circular economy through the encouragement of the recovery of industrial waste.
T2  - Tehnika
T1  - Zakonska regulativa u upravljanju čvrstim industrijskim otpadom u Srbiji - izazovi na putu razvoja cirkularne ekonomije
T1  - Legal regulations of industrial solid waste management in Serbia: Challenges on the way of developing the circular economy
VL  - 79
IS  - 1
SP  - 47
EP  - 54
DO  - 10.5937/tehnika2401047N
ER  - 
@article{
author = "Nišić, Dragana and Pantelić, Uroš and Nišić, Neda",
year = "2024",
abstract = "Upravljanje čvrstim industrijskim otpadom je regulisan kroz nekoliko zakonskih akata u Srbiji i trenutno se aktivno radi na unapređenju zakonskih normi koje regulišu prevođenje otpada u materije koje nisu otpad, kako bi se ostvarili ciljevi postavljeni Zelenom agendom i Nacionalnim planom upravljanja otpadom. U ovom radu dat je pregled zakonskih propisa kojim se uređuje upravljanje ot-padom, sa posebnim osvrtom na akte i članove akata koji regulišu ponovnu upotrebu čvrstog industrijskog otpada. Navedene su moguće prepreke i nedoumice koje se mogu javiti prilikom tumačenja zakonskih odredbi sa fokusom na sličnostima i razlikama u smernicama za prevođenje otpada u nusproizvod i materiju koja je izgubila status otpada, mogućnosti ponovnog iskorišćenja opasnog otpada i specifičnosti uvoza otpada koji više nije otpad u Srbiju iz neke od zemalja Evropske unije. Kroz konkretan primer prevođenja letećeg pepela u korisnu cementu sirovinu ilustrovane su neke poteškoće na koje se nailazilo do sada u praksi. U zaključku ovog rada predložene su određene mere, kojima bi se navedene prepreke u implementaciji cirkularne ekonomije kroz podsticaj ponovnog iskorišćenja industrijskog otpada, prevazišle., The management of industrial solid waste is regulated through several legal acts in Serbia, and in the last few years intensive work has been done to improve the legal norms that regulate the conversion of waste into materials that are no longer waste, in order to achieve the goals, set by the Green Agenda and the National Waste Management Plan. This paper provides an overview of the legal regulations which are regulating waste management, with special reference to acts and articles of acts that regulate the reuse and recovery of solid industrial waste. Possible obstacles and doubts that may arise when interpreting legal provisions are listed, with a focus on similarities and differences in the guidelines for converting waste into a by-product and material with and of waste status, the possibility of hazardous waste recovery, and the specifics of importing waste that is no longer waste into Serbia from one of the countries of the European Union. Through an example of converting fly ash into a useful cementitious raw material, some difficulties that have been encountered so far in practice are illustrated. In the conclusion of this paper, certain measures were proposed to overcome the mentioned obstacles in the implementation of the circular economy through the encouragement of the recovery of industrial waste.",
journal = "Tehnika",
title = "Zakonska regulativa u upravljanju čvrstim industrijskim otpadom u Srbiji - izazovi na putu razvoja cirkularne ekonomije, Legal regulations of industrial solid waste management in Serbia: Challenges on the way of developing the circular economy",
volume = "79",
number = "1",
pages = "47-54",
doi = "10.5937/tehnika2401047N"
}
Nišić, D., Pantelić, U.,& Nišić, N.. (2024). Zakonska regulativa u upravljanju čvrstim industrijskim otpadom u Srbiji - izazovi na putu razvoja cirkularne ekonomije. in Tehnika, 79(1), 47-54.
https://doi.org/10.5937/tehnika2401047N
Nišić D, Pantelić U, Nišić N. Zakonska regulativa u upravljanju čvrstim industrijskim otpadom u Srbiji - izazovi na putu razvoja cirkularne ekonomije. in Tehnika. 2024;79(1):47-54.
doi:10.5937/tehnika2401047N .
Nišić, Dragana, Pantelić, Uroš, Nišić, Neda, "Zakonska regulativa u upravljanju čvrstim industrijskim otpadom u Srbiji - izazovi na putu razvoja cirkularne ekonomije" in Tehnika, 79, no. 1 (2024):47-54,
https://doi.org/10.5937/tehnika2401047N . .

Activated carbon from almond pits as low-cost material for electrochemical application

Nikolić, Katarina; Kragović, Milan; Stojmenović, Marija; Vasić, Andrijana; Kandić, Irina; Nišić, Neda; Gulicovski, Jelena J.

(Belgrade : University of Belgrade : Faculty of Mining and Geology, 2023)

TY  - CONF
AU  - Nikolić, Katarina
AU  - Kragović, Milan
AU  - Stojmenović, Marija
AU  - Vasić, Andrijana
AU  - Kandić, Irina
AU  - Nišić, Neda
AU  - Gulicovski, Jelena J.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11978
AB  - In this study, a novel porous carbonaceous material, which has been synthesized from almond pits as precursors, has been characterized for the purpose of application as electrodes in electrochemical sensors. The powdery sample of activated carbonized almond pits was analyzed by X-ray diffraction (XRD) and Diffuse Reflectance Infrared Fourier Spectroscopy (DRIFT). Besides, the electrochemical properties of the sample were investigated in a three-electrode system using a CHI potentiostat. Obtained XRD diffractogram confirmed the amorphous phase of the sample, while DRIFT showed the presence of different functional groups. According to the results, synthesized carbonaceous material was found to possess great potential as a low-cost and eco-friendly material for electrochemical applications.
PB  - Belgrade : University of Belgrade : Faculty of Mining and Geology
C3  - MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
T1  - Activated carbon from almond pits as low-cost material for electrochemical application
SP  - 308
EP  - 311
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11978
ER  - 
@conference{
author = "Nikolić, Katarina and Kragović, Milan and Stojmenović, Marija and Vasić, Andrijana and Kandić, Irina and Nišić, Neda and Gulicovski, Jelena J.",
year = "2023",
abstract = "In this study, a novel porous carbonaceous material, which has been synthesized from almond pits as precursors, has been characterized for the purpose of application as electrodes in electrochemical sensors. The powdery sample of activated carbonized almond pits was analyzed by X-ray diffraction (XRD) and Diffuse Reflectance Infrared Fourier Spectroscopy (DRIFT). Besides, the electrochemical properties of the sample were investigated in a three-electrode system using a CHI potentiostat. Obtained XRD diffractogram confirmed the amorphous phase of the sample, while DRIFT showed the presence of different functional groups. According to the results, synthesized carbonaceous material was found to possess great potential as a low-cost and eco-friendly material for electrochemical applications.",
publisher = "Belgrade : University of Belgrade : Faculty of Mining and Geology",
journal = "MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book",
title = "Activated carbon from almond pits as low-cost material for electrochemical application",
pages = "308-311",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11978"
}
Nikolić, K., Kragović, M., Stojmenović, M., Vasić, A., Kandić, I., Nišić, N.,& Gulicovski, J. J.. (2023). Activated carbon from almond pits as low-cost material for electrochemical application. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
Belgrade : University of Belgrade : Faculty of Mining and Geology., 308-311.
https://hdl.handle.net/21.15107/rcub_vinar_11978
Nikolić K, Kragović M, Stojmenović M, Vasić A, Kandić I, Nišić N, Gulicovski JJ. Activated carbon from almond pits as low-cost material for electrochemical application. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book. 2023;:308-311.
https://hdl.handle.net/21.15107/rcub_vinar_11978 .
Nikolić, Katarina, Kragović, Milan, Stojmenović, Marija, Vasić, Andrijana, Kandić, Irina, Nišić, Neda, Gulicovski, Jelena J., "Activated carbon from almond pits as low-cost material for electrochemical application" in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book (2023):308-311,
https://hdl.handle.net/21.15107/rcub_vinar_11978 .

Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell

Nišić, Neda; Kragović, Milan; Žunić, Milan; Gulicovski, Jelena; Vasić, Andrijana; Kandić, Irina; Stojmenović, Marija

(Belgrade : University of Belgrade : Faculty of Mining and Geology, 2023)

TY  - CONF
AU  - Nišić, Neda
AU  - Kragović, Milan
AU  - Žunić, Milan
AU  - Gulicovski, Jelena
AU  - Vasić, Andrijana
AU  - Kandić, Irina
AU  - Stojmenović, Marija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11996
AB  - Nanopowders of CeO2 as a major component and different rare earth oxides added as dopants were synthesized using the modified glycine-nitrate procedure (MGNP) for the purpose of fabrication of electrolytes for IT-SOFC. Synthesized nanopowder was characterized by XRPD and Raman spectroscopy. According to results, single phase solid solution of fluorite structure were evidenced. Produced powder was then subjected to sintering at 1550 ºC for 2 h in air. By SEM analysis, highly ordered microstructure of sintered sample was verified, while EDS method revealed that the sintered sample have chemical composition very similar to a nominal one. Afterwards, the ionic conductivity of the sintered sample was measured by EIS method. The highest value was obtained at 700 ºC, amounting to 1.92×10-1 Ω-1 cm-1 .
PB  - Belgrade : University of Belgrade : Faculty of Mining and Geology
C3  - MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
T1  - Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell
SP  - 316
EP  - 320
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11996
ER  - 
@conference{
author = "Nišić, Neda and Kragović, Milan and Žunić, Milan and Gulicovski, Jelena and Vasić, Andrijana and Kandić, Irina and Stojmenović, Marija",
year = "2023",
abstract = "Nanopowders of CeO2 as a major component and different rare earth oxides added as dopants were synthesized using the modified glycine-nitrate procedure (MGNP) for the purpose of fabrication of electrolytes for IT-SOFC. Synthesized nanopowder was characterized by XRPD and Raman spectroscopy. According to results, single phase solid solution of fluorite structure were evidenced. Produced powder was then subjected to sintering at 1550 ºC for 2 h in air. By SEM analysis, highly ordered microstructure of sintered sample was verified, while EDS method revealed that the sintered sample have chemical composition very similar to a nominal one. Afterwards, the ionic conductivity of the sintered sample was measured by EIS method. The highest value was obtained at 700 ºC, amounting to 1.92×10-1 Ω-1 cm-1 .",
publisher = "Belgrade : University of Belgrade : Faculty of Mining and Geology",
journal = "MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book",
title = "Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell",
pages = "316-320",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11996"
}
Nišić, N., Kragović, M., Žunić, M., Gulicovski, J., Vasić, A., Kandić, I.,& Stojmenović, M.. (2023). Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
Belgrade : University of Belgrade : Faculty of Mining and Geology., 316-320.
https://hdl.handle.net/21.15107/rcub_vinar_11996
Nišić N, Kragović M, Žunić M, Gulicovski J, Vasić A, Kandić I, Stojmenović M. Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book. 2023;:316-320.
https://hdl.handle.net/21.15107/rcub_vinar_11996 .
Nišić, Neda, Kragović, Milan, Žunić, Milan, Gulicovski, Jelena, Vasić, Andrijana, Kandić, Irina, Stojmenović, Marija, "Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell" in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book (2023):316-320,
https://hdl.handle.net/21.15107/rcub_vinar_11996 .

Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste

Nišić, Neda; Kragović, Milan; Gulicovski, Jelena; Nikolić, Katarina; Vasić, Andrijana; Žunić, Milan; Stojmenović, Marija

(Belgrade : University of Belgrade : Faculty of Mining and Geology, 2023)

TY  - CONF
AU  - Nišić, Neda
AU  - Kragović, Milan
AU  - Gulicovski, Jelena
AU  - Nikolić, Katarina
AU  - Vasić, Andrijana
AU  - Žunić, Milan
AU  - Stojmenović, Marija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11997
AB  - In the present paper, possible application of novel ceramic adhesives with implementation of waste sludge for bonding of heating devices constructions was studied. For a comparison, five different samples with increasing waste addition percentage were prepared and their performance as heat-resistant adhesives were evaluated in terms of chemical and thermostability as well as ecological safety. Based on ICP-OES analysis it was observed that only sample GC20 is not ecologically-safe due to high level of Cu+ concentration. By withstanding thermal treatment in the range of 200-800˚C for over 100h, all adhesive samples showed satisfactory thermostability. This research confirms the great potential of the studied materials for application as uncostly and eco-friendly adhesives for industrial purpose.
PB  - Belgrade : University of Belgrade : Faculty of Mining and Geology
C3  - MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
T1  - Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste
SP  - 312
EP  - 315
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11997
ER  - 
@conference{
author = "Nišić, Neda and Kragović, Milan and Gulicovski, Jelena and Nikolić, Katarina and Vasić, Andrijana and Žunić, Milan and Stojmenović, Marija",
year = "2023",
abstract = "In the present paper, possible application of novel ceramic adhesives with implementation of waste sludge for bonding of heating devices constructions was studied. For a comparison, five different samples with increasing waste addition percentage were prepared and their performance as heat-resistant adhesives were evaluated in terms of chemical and thermostability as well as ecological safety. Based on ICP-OES analysis it was observed that only sample GC20 is not ecologically-safe due to high level of Cu+ concentration. By withstanding thermal treatment in the range of 200-800˚C for over 100h, all adhesive samples showed satisfactory thermostability. This research confirms the great potential of the studied materials for application as uncostly and eco-friendly adhesives for industrial purpose.",
publisher = "Belgrade : University of Belgrade : Faculty of Mining and Geology",
journal = "MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book",
title = "Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste",
pages = "312-315",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11997"
}
Nišić, N., Kragović, M., Gulicovski, J., Nikolić, K., Vasić, A., Žunić, M.,& Stojmenović, M.. (2023). Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
Belgrade : University of Belgrade : Faculty of Mining and Geology., 312-315.
https://hdl.handle.net/21.15107/rcub_vinar_11997
Nišić N, Kragović M, Gulicovski J, Nikolić K, Vasić A, Žunić M, Stojmenović M. Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book. 2023;:312-315.
https://hdl.handle.net/21.15107/rcub_vinar_11997 .
Nišić, Neda, Kragović, Milan, Gulicovski, Jelena, Nikolić, Katarina, Vasić, Andrijana, Žunić, Milan, Stojmenović, Marija, "Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste" in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book (2023):312-315,
https://hdl.handle.net/21.15107/rcub_vinar_11997 .

Xanthate removal as a function of pH and the point of zero charge

Vasić, Andrijana; Stojmenović, Marija; Nikolić, Katarina; Nišić, Neda; Gulicovski, Jelena; Lišanin, Radmila; Kragović, Milan

(Belgrade : University of Belgrade : Faculty of Mining and Geology, 2023)

TY  - CONF
AU  - Vasić, Andrijana
AU  - Stojmenović, Marija
AU  - Nikolić, Katarina
AU  - Nišić, Neda
AU  - Gulicovski, Jelena
AU  - Lišanin, Radmila
AU  - Kragović, Milan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11999
AB  - Because of their widespread use as reagents in the flotation processing of sulphide ores, xanthates are largely found in tailings as residues. Regrettably, it is known that xanthates are not stable compounds and their decomposition generates carbon disulfide (CS2), a substance that is considered toxic. In this study, the chemical stability of xanthate was evaluated by UV/Vis spectroscopy, as a function of pH and time. The zero charge point of modified waste slag was also determined. The obtained results showed that the lowest degree of xanthate degradation is for the pH=10 and was 24.72%. For different concentrations of the KNO3 (0.1, 0.01, and 0.001 mol/dm3 ) the point of zero charge of the modified waste slag was 7.28, respectively
PB  - Belgrade : University of Belgrade : Faculty of Mining and Geology
C3  - MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
T1  - Xanthate removal as a function of pH and the point of zero charge
SP  - 325
EP  - 328
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11999
ER  - 
@conference{
author = "Vasić, Andrijana and Stojmenović, Marija and Nikolić, Katarina and Nišić, Neda and Gulicovski, Jelena and Lišanin, Radmila and Kragović, Milan",
year = "2023",
abstract = "Because of their widespread use as reagents in the flotation processing of sulphide ores, xanthates are largely found in tailings as residues. Regrettably, it is known that xanthates are not stable compounds and their decomposition generates carbon disulfide (CS2), a substance that is considered toxic. In this study, the chemical stability of xanthate was evaluated by UV/Vis spectroscopy, as a function of pH and time. The zero charge point of modified waste slag was also determined. The obtained results showed that the lowest degree of xanthate degradation is for the pH=10 and was 24.72%. For different concentrations of the KNO3 (0.1, 0.01, and 0.001 mol/dm3 ) the point of zero charge of the modified waste slag was 7.28, respectively",
publisher = "Belgrade : University of Belgrade : Faculty of Mining and Geology",
journal = "MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book",
title = "Xanthate removal as a function of pH and the point of zero charge",
pages = "325-328",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11999"
}
Vasić, A., Stojmenović, M., Nikolić, K., Nišić, N., Gulicovski, J., Lišanin, R.,& Kragović, M.. (2023). Xanthate removal as a function of pH and the point of zero charge. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
Belgrade : University of Belgrade : Faculty of Mining and Geology., 325-328.
https://hdl.handle.net/21.15107/rcub_vinar_11999
Vasić A, Stojmenović M, Nikolić K, Nišić N, Gulicovski J, Lišanin R, Kragović M. Xanthate removal as a function of pH and the point of zero charge. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book. 2023;:325-328.
https://hdl.handle.net/21.15107/rcub_vinar_11999 .
Vasić, Andrijana, Stojmenović, Marija, Nikolić, Katarina, Nišić, Neda, Gulicovski, Jelena, Lišanin, Radmila, Kragović, Milan, "Xanthate removal as a function of pH and the point of zero charge" in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book (2023):325-328,
https://hdl.handle.net/21.15107/rcub_vinar_11999 .

The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials

Nišić, Neda; Kragović, Milan; Gulicovski, Jelena; Žunić, Milan; Basoli, Francesco; Gordić, Milan; Stojmenović, Marija

(2023)

TY  - JOUR
AU  - Nišić, Neda
AU  - Kragović, Milan
AU  - Gulicovski, Jelena
AU  - Žunić, Milan
AU  - Basoli, Francesco
AU  - Gordić, Milan
AU  - Stojmenović, Marija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11455
AB  - In recent years, the interest of the scientific community has become focused on the integration of circular economy principles by eliminating end-of-life concepts and forming zero-waste strategies. The present paper suggests the possible application of innovative, eco-friendly, cost-effective, and highly efficient ceramic materials with the partial implementation of aluminosilicate-based waste in the form of wastewater sludge in advanced technology solutions. The specific objective was to demonstrate the effective utilization of the investigated waste in the production of refractory adhesives and/or sealants for Intermediate-Temperature Solid-Oxide Fuel Cells (IT-SOFCs). Different physical–mechanical and chemical properties were determined along with the performance of leaching tests, the thermal cycling procedure, and leakage tests in a single cell. Based on the maintenance of mechanical integrity after thermal cycling and satisfying crystal and microstructural stability after high-temperature treatment, it was concluded that the investigated materials may be considered promising candidates for application as heat-resistant adhesives for connecting components in heating systems. However, they were not found to be applicable as sealants for IT-SOFCs in raw form according to the failure of testing in a single cell. Still, requirements for this purpose could be met after certain modifications of the composition and synthesis methodology, which presents the major initiative for our further research in this field. © 2023 by the authors.
T2  - Applied Sciences (Switzerland)
T1  - The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials
VL  - 13
IS  - 16
SP  - 9044
DO  - 10.3390/app13169044
ER  - 
@article{
author = "Nišić, Neda and Kragović, Milan and Gulicovski, Jelena and Žunić, Milan and Basoli, Francesco and Gordić, Milan and Stojmenović, Marija",
year = "2023",
abstract = "In recent years, the interest of the scientific community has become focused on the integration of circular economy principles by eliminating end-of-life concepts and forming zero-waste strategies. The present paper suggests the possible application of innovative, eco-friendly, cost-effective, and highly efficient ceramic materials with the partial implementation of aluminosilicate-based waste in the form of wastewater sludge in advanced technology solutions. The specific objective was to demonstrate the effective utilization of the investigated waste in the production of refractory adhesives and/or sealants for Intermediate-Temperature Solid-Oxide Fuel Cells (IT-SOFCs). Different physical–mechanical and chemical properties were determined along with the performance of leaching tests, the thermal cycling procedure, and leakage tests in a single cell. Based on the maintenance of mechanical integrity after thermal cycling and satisfying crystal and microstructural stability after high-temperature treatment, it was concluded that the investigated materials may be considered promising candidates for application as heat-resistant adhesives for connecting components in heating systems. However, they were not found to be applicable as sealants for IT-SOFCs in raw form according to the failure of testing in a single cell. Still, requirements for this purpose could be met after certain modifications of the composition and synthesis methodology, which presents the major initiative for our further research in this field. © 2023 by the authors.",
journal = "Applied Sciences (Switzerland)",
title = "The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials",
volume = "13",
number = "16",
pages = "9044",
doi = "10.3390/app13169044"
}
Nišić, N., Kragović, M., Gulicovski, J., Žunić, M., Basoli, F., Gordić, M.,& Stojmenović, M.. (2023). The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials. in Applied Sciences (Switzerland), 13(16), 9044.
https://doi.org/10.3390/app13169044
Nišić N, Kragović M, Gulicovski J, Žunić M, Basoli F, Gordić M, Stojmenović M. The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials. in Applied Sciences (Switzerland). 2023;13(16):9044.
doi:10.3390/app13169044 .
Nišić, Neda, Kragović, Milan, Gulicovski, Jelena, Žunić, Milan, Basoli, Francesco, Gordić, Milan, Stojmenović, Marija, "The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials" in Applied Sciences (Switzerland), 13, no. 16 (2023):9044,
https://doi.org/10.3390/app13169044 . .
1

Removal of potentially toxic cyanobacteria by using activated carbons obtained from biowaste

Kandić, Irina; Kragović, Milan; Gulicovski, Jelena; Nikolić, Katarina; Nišić, Neda; Karadžić, Vesna; Stojmenović, Marija

(Belgrade : University of Belgrade : Faculty of Mining and Geology, 2023)

TY  - CONF
AU  - Kandić, Irina
AU  - Kragović, Milan
AU  - Gulicovski, Jelena
AU  - Nikolić, Katarina
AU  - Nišić, Neda
AU  - Karadžić, Vesna
AU  - Stojmenović, Marija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11977
AB  - This scientific study investigated the use of activated carbon obtained from black alder cone-like flowers for the adsorption of cyanobacteria cells and cyanotoxins from raw water collected from Aleksandrovac Lake. The material was prepared by carbonization and activation, and the water sample was analysed for microcystin and cylindrospermopsin using LC-MS. The results showed that the lake had a high level of Cyanobacteria, making it unsafe for recreational activities. After treatment with the activated carbon, the removal efficiency was 99,8 %, and with no cyanotoxins remaining. The dominant cyanobacteria species was Raphidiopsis raciborskii, which is a producer of cylindrospermopsin. The study demonstrated the potential of activated carbon for removing harmful cyanobacteria and cyanotoxins from water sources.
PB  - Belgrade : University of Belgrade : Faculty of Mining and Geology
C3  - MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
T1  - Removal of potentially toxic cyanobacteria by using
activated carbons obtained from biowaste
SP  - 286
EP  - 290
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11977
ER  - 
@conference{
author = "Kandić, Irina and Kragović, Milan and Gulicovski, Jelena and Nikolić, Katarina and Nišić, Neda and Karadžić, Vesna and Stojmenović, Marija",
year = "2023",
abstract = "This scientific study investigated the use of activated carbon obtained from black alder cone-like flowers for the adsorption of cyanobacteria cells and cyanotoxins from raw water collected from Aleksandrovac Lake. The material was prepared by carbonization and activation, and the water sample was analysed for microcystin and cylindrospermopsin using LC-MS. The results showed that the lake had a high level of Cyanobacteria, making it unsafe for recreational activities. After treatment with the activated carbon, the removal efficiency was 99,8 %, and with no cyanotoxins remaining. The dominant cyanobacteria species was Raphidiopsis raciborskii, which is a producer of cylindrospermopsin. The study demonstrated the potential of activated carbon for removing harmful cyanobacteria and cyanotoxins from water sources.",
publisher = "Belgrade : University of Belgrade : Faculty of Mining and Geology",
journal = "MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book",
title = "Removal of potentially toxic cyanobacteria by using
activated carbons obtained from biowaste",
pages = "286-290",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11977"
}
Kandić, I., Kragović, M., Gulicovski, J., Nikolić, K., Nišić, N., Karadžić, V.,& Stojmenović, M.. (2023). Removal of potentially toxic cyanobacteria by using
activated carbons obtained from biowaste. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
Belgrade : University of Belgrade : Faculty of Mining and Geology., 286-290.
https://hdl.handle.net/21.15107/rcub_vinar_11977
Kandić I, Kragović M, Gulicovski J, Nikolić K, Nišić N, Karadžić V, Stojmenović M. Removal of potentially toxic cyanobacteria by using
activated carbons obtained from biowaste. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book. 2023;:286-290.
https://hdl.handle.net/21.15107/rcub_vinar_11977 .
Kandić, Irina, Kragović, Milan, Gulicovski, Jelena, Nikolić, Katarina, Nišić, Neda, Karadžić, Vesna, Stojmenović, Marija, "Removal of potentially toxic cyanobacteria by using
activated carbons obtained from biowaste" in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book (2023):286-290,
https://hdl.handle.net/21.15107/rcub_vinar_11977 .

Characterization of active carbon materials obtained from bio waste for potential use in water purification

Kandić, Irina; Kragović, Milan; Vasić, Andrijana; Nišić, Neda; Nikolić, Katarina; Gulicovski, Jelena; Stojmenović, Marija

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2022)

TY  - CONF
AU  - Kandić, Irina
AU  - Kragović, Milan
AU  - Vasić, Andrijana
AU  - Nišić, Neda
AU  - Nikolić, Katarina
AU  - Gulicovski, Jelena
AU  - Stojmenović, Marija
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11958
AB  - Adsorption is one of the well-known methods in the removal of various pollutants from water bodies. The activated carbon material has great potential in water purification as an adsorbent. In process of adsorption various pollutants from water, such as different type of pathogens and toxins that can be potential risk for human health, can be effectively removed by activated carbon. The aim of this study is detail characterization of newly synthesized activated carbon materials from biowaste. Dried date palm leaf stalk (Phoenix dactylifera L.) and black alder cone-like flowers (Alnus glutinosa L.) have been chosen as bio-waste precursors. The activated carbon materials were firstly carbonized in atmosphere of N2 and then activated in atmosphere of CO2. Both processes are performed at 750 °C during 1 h. The yields of materials were 36.5 % and 24.7 % made of datepalm leaf stalk (P_AC) and black alder cone-like (A_AC) flowers, respectively. The commercial activated carbon has been characterized in order to compare with synthesized materials. For structural and chemical properties of materials was characterized in detail by: X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), low temperature N2 physisorption and Field emission scanning electron microscopy (FESEM). According to those results, materials obtained from date palm leaf stalk and black alder fruits show that newly synthesized materials have properties of an adsorbent with good potential for usage in water purification from different types of pollutants.
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
T1  - Characterization of active carbon materials obtained from bio waste for potential use in water purification
SP  - 38
EP  - 38
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11958
ER  - 
@conference{
author = "Kandić, Irina and Kragović, Milan and Vasić, Andrijana and Nišić, Neda and Nikolić, Katarina and Gulicovski, Jelena and Stojmenović, Marija",
year = "2022",
abstract = "Adsorption is one of the well-known methods in the removal of various pollutants from water bodies. The activated carbon material has great potential in water purification as an adsorbent. In process of adsorption various pollutants from water, such as different type of pathogens and toxins that can be potential risk for human health, can be effectively removed by activated carbon. The aim of this study is detail characterization of newly synthesized activated carbon materials from biowaste. Dried date palm leaf stalk (Phoenix dactylifera L.) and black alder cone-like flowers (Alnus glutinosa L.) have been chosen as bio-waste precursors. The activated carbon materials were firstly carbonized in atmosphere of N2 and then activated in atmosphere of CO2. Both processes are performed at 750 °C during 1 h. The yields of materials were 36.5 % and 24.7 % made of datepalm leaf stalk (P_AC) and black alder cone-like (A_AC) flowers, respectively. The commercial activated carbon has been characterized in order to compare with synthesized materials. For structural and chemical properties of materials was characterized in detail by: X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), low temperature N2 physisorption and Field emission scanning electron microscopy (FESEM). According to those results, materials obtained from date palm leaf stalk and black alder fruits show that newly synthesized materials have properties of an adsorbent with good potential for usage in water purification from different types of pollutants.",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts",
title = "Characterization of active carbon materials obtained from bio waste for potential use in water purification",
pages = "38-38",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11958"
}
Kandić, I., Kragović, M., Vasić, A., Nišić, N., Nikolić, K., Gulicovski, J.,& Stojmenović, M.. (2022). Characterization of active carbon materials obtained from bio waste for potential use in water purification. in 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 38-38.
https://hdl.handle.net/21.15107/rcub_vinar_11958
Kandić I, Kragović M, Vasić A, Nišić N, Nikolić K, Gulicovski J, Stojmenović M. Characterization of active carbon materials obtained from bio waste for potential use in water purification. in 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts. 2022;:38-38.
https://hdl.handle.net/21.15107/rcub_vinar_11958 .
Kandić, Irina, Kragović, Milan, Vasić, Andrijana, Nišić, Neda, Nikolić, Katarina, Gulicovski, Jelena, Stojmenović, Marija, "Characterization of active carbon materials obtained from bio waste for potential use in water purification" in 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts (2022):38-38,
https://hdl.handle.net/21.15107/rcub_vinar_11958 .

Xanthate absorption kinetics as a function of the starting concentration with the use of the waste slag as adsorbent

Nedeljković, Andrijana; Nišić, Neda; Nikolić, Katarina; Kandić, Irina; Stojmenović, Marija; Gulicovski, Jelena; Kragović, Milan

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2022)

TY  - CONF
AU  - Nedeljković, Andrijana
AU  - Nišić, Neda
AU  - Nikolić, Katarina
AU  - Kandić, Irina
AU  - Stojmenović, Marija
AU  - Gulicovski, Jelena
AU  - Kragović, Milan
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11957
AB  - In order to avoid environmental issues considering disposal of great volumes of waste generated from the mining industry processes there is a tendency among researchers to find potential use of these harmful by-products. Waste slag is one such waste product since the content of different undesirable elements like cadmium, arsenic, zinc and other heavy metals may be at a level that can potentially endanger the environment and cause public health issues. On the other hand, tailings generated in the flotation facilities are also considered to be environmentally harmful because of different residual organic reagents that are applied in the process. As it is well-known, xanthates are the most widely used reagents in flotation processing of the sulfide ores, and, therefore largely present in tailings. Besides, xanthates are reported to pose toxicity and numerous negative impacts from the ecological point of view. That explains why it is of great importance to find efficient and low-cost routes for minimizing their remaining levels in tailings, therefore exposure to environment. In this study, xanthate absorption by using of the waste slag as adsorbent was investigated. For that purpose, three different starting concentrations of xanthates were selected, -20, 50 and 90 mg/l. The mass of the absorbent i.e. waste slag put into 50 ml of xanthate solution amounted to 0.01 g. Experiment was conducted on room temperature while pH value was set to be 10. The percentage of the total xanthates content absorbed was evaluated after the period of 24 h. Obtained results indicated that potential reuse of the waste slag for the removal of xanthates, may be justified and after 24 h, 98 %, 58 % and 62 % of the xanthates were adsorbed, respectively. However, further examination is needed in terms of better understanding of xanthate absorption mechanisms and improvement of waste slag absorption efficiency.
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
T1  - Xanthate absorption kinetics as a function of the starting concentration with the use of the waste slag as adsorbent
SP  - 52
EP  - 52
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11957
ER  - 
@conference{
author = "Nedeljković, Andrijana and Nišić, Neda and Nikolić, Katarina and Kandić, Irina and Stojmenović, Marija and Gulicovski, Jelena and Kragović, Milan",
year = "2022",
abstract = "In order to avoid environmental issues considering disposal of great volumes of waste generated from the mining industry processes there is a tendency among researchers to find potential use of these harmful by-products. Waste slag is one such waste product since the content of different undesirable elements like cadmium, arsenic, zinc and other heavy metals may be at a level that can potentially endanger the environment and cause public health issues. On the other hand, tailings generated in the flotation facilities are also considered to be environmentally harmful because of different residual organic reagents that are applied in the process. As it is well-known, xanthates are the most widely used reagents in flotation processing of the sulfide ores, and, therefore largely present in tailings. Besides, xanthates are reported to pose toxicity and numerous negative impacts from the ecological point of view. That explains why it is of great importance to find efficient and low-cost routes for minimizing their remaining levels in tailings, therefore exposure to environment. In this study, xanthate absorption by using of the waste slag as adsorbent was investigated. For that purpose, three different starting concentrations of xanthates were selected, -20, 50 and 90 mg/l. The mass of the absorbent i.e. waste slag put into 50 ml of xanthate solution amounted to 0.01 g. Experiment was conducted on room temperature while pH value was set to be 10. The percentage of the total xanthates content absorbed was evaluated after the period of 24 h. Obtained results indicated that potential reuse of the waste slag for the removal of xanthates, may be justified and after 24 h, 98 %, 58 % and 62 % of the xanthates were adsorbed, respectively. However, further examination is needed in terms of better understanding of xanthate absorption mechanisms and improvement of waste slag absorption efficiency.",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts",
title = "Xanthate absorption kinetics as a function of the starting concentration with the use of the waste slag as adsorbent",
pages = "52-52",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11957"
}
Nedeljković, A., Nišić, N., Nikolić, K., Kandić, I., Stojmenović, M., Gulicovski, J.,& Kragović, M.. (2022). Xanthate absorption kinetics as a function of the starting concentration with the use of the waste slag as adsorbent. in 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 52-52.
https://hdl.handle.net/21.15107/rcub_vinar_11957
Nedeljković A, Nišić N, Nikolić K, Kandić I, Stojmenović M, Gulicovski J, Kragović M. Xanthate absorption kinetics as a function of the starting concentration with the use of the waste slag as adsorbent. in 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts. 2022;:52-52.
https://hdl.handle.net/21.15107/rcub_vinar_11957 .
Nedeljković, Andrijana, Nišić, Neda, Nikolić, Katarina, Kandić, Irina, Stojmenović, Marija, Gulicovski, Jelena, Kragović, Milan, "Xanthate absorption kinetics as a function of the starting concentration with the use of the waste slag as adsorbent" in 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts (2022):52-52,
https://hdl.handle.net/21.15107/rcub_vinar_11957 .

Characterization of high temperature ceramic composite sealants (CCS) with addition of alumosilicate based waste material for the potential use in it-sofc

Nišić, Neda; Kragović, Milan; Nedeljković, Andrijana; Kandić, Irina; Nikolić, Katarina; Gulicovski, Jelena; Stojmenović, Marija

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2022)

TY  - CONF
AU  - Nišić, Neda
AU  - Kragović, Milan
AU  - Nedeljković, Andrijana
AU  - Kandić, Irina
AU  - Nikolić, Katarina
AU  - Gulicovski, Jelena
AU  - Stojmenović, Marija
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11959
AB  - In the present paper, possible application of novel concept synthesis method of ceramic composite sealants (CCS) with implementation of alumosilicate-based waste material in intermediate temperature solid oxide fuel cells (IT-SOFC) was investigated. Besides two different basic variants of alumina matrix nanocomposites stabilized by rare earths and carbon materials (CCS-RE and CCS-C), for this purpose two additional sealant compositions with 5 wt.% addition of waste material (CCS-RE5 and CCS-C5) were designated for a comparative study. The aim of this research was to characterize the waste material, as well as the starting components used for developing ceramic composites through various characterization techniques. Analytical procedures for determining chemical composition with focus on heavy metal content in waste was performed in order to ensure the waste is ecologically acceptable to be used as an additive. Besides, the crystalline phase composition of the raw materials as well as of the sealant compositions was determined by X-ray diffraction (XRD) analysis. Finally, obtained results revealed that this research may provide the possible solution of forming a cost-effective, environmentally-friendly and high-efficient ceramic sealants for application in IT-SOFC by incorporating waste materials in its composition, without significant negative effects on its performance and main properties.
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
T1  - Characterization of high temperature ceramic
composite sealants (CCS) with addition of
alumosilicate based waste material for the
potential use in it-sofc
SP  - 48
EP  - 48
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11959
ER  - 
@conference{
author = "Nišić, Neda and Kragović, Milan and Nedeljković, Andrijana and Kandić, Irina and Nikolić, Katarina and Gulicovski, Jelena and Stojmenović, Marija",
year = "2022",
abstract = "In the present paper, possible application of novel concept synthesis method of ceramic composite sealants (CCS) with implementation of alumosilicate-based waste material in intermediate temperature solid oxide fuel cells (IT-SOFC) was investigated. Besides two different basic variants of alumina matrix nanocomposites stabilized by rare earths and carbon materials (CCS-RE and CCS-C), for this purpose two additional sealant compositions with 5 wt.% addition of waste material (CCS-RE5 and CCS-C5) were designated for a comparative study. The aim of this research was to characterize the waste material, as well as the starting components used for developing ceramic composites through various characterization techniques. Analytical procedures for determining chemical composition with focus on heavy metal content in waste was performed in order to ensure the waste is ecologically acceptable to be used as an additive. Besides, the crystalline phase composition of the raw materials as well as of the sealant compositions was determined by X-ray diffraction (XRD) analysis. Finally, obtained results revealed that this research may provide the possible solution of forming a cost-effective, environmentally-friendly and high-efficient ceramic sealants for application in IT-SOFC by incorporating waste materials in its composition, without significant negative effects on its performance and main properties.",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts",
title = "Characterization of high temperature ceramic
composite sealants (CCS) with addition of
alumosilicate based waste material for the
potential use in it-sofc",
pages = "48-48",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11959"
}
Nišić, N., Kragović, M., Nedeljković, A., Kandić, I., Nikolić, K., Gulicovski, J.,& Stojmenović, M.. (2022). Characterization of high temperature ceramic
composite sealants (CCS) with addition of
alumosilicate based waste material for the
potential use in it-sofc. in 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 48-48.
https://hdl.handle.net/21.15107/rcub_vinar_11959
Nišić N, Kragović M, Nedeljković A, Kandić I, Nikolić K, Gulicovski J, Stojmenović M. Characterization of high temperature ceramic
composite sealants (CCS) with addition of
alumosilicate based waste material for the
potential use in it-sofc. in 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts. 2022;:48-48.
https://hdl.handle.net/21.15107/rcub_vinar_11959 .
Nišić, Neda, Kragović, Milan, Nedeljković, Andrijana, Kandić, Irina, Nikolić, Katarina, Gulicovski, Jelena, Stojmenović, Marija, "Characterization of high temperature ceramic
composite sealants (CCS) with addition of
alumosilicate based waste material for the
potential use in it-sofc" in 6CSCS : Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials : Book of abstracts (2022):48-48,
https://hdl.handle.net/21.15107/rcub_vinar_11959 .

Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs

Stojmenović, Marija; Nišić, Neda; Žunić, Milan; Basoli, Francesco; Gulicovki, Jelena; Ristović, Ivica; Kragović, Milan M.

(2022)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Nišić, Neda
AU  - Žunić, Milan
AU  - Basoli, Francesco
AU  - Gulicovki, Jelena
AU  - Ristović, Ivica
AU  - Kragović, Milan M.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10622
AB  - Nanosized multi-doped ceria with composition Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-δ (CNSGDY) as perspective solid ionic conductor was obtained by modified glycine-nitrate procedure (MGNP) and room temperature self-propagating reaction (SPRT). The pressed pellets of both powders were sintered at 1550°C for 2 h in an air atmosphere. The obtained sintered samples were characterized by XRPD, Raman spectroscopy, FESEM, EDS and EIS methods. Despite a high temperature of sintering, XRPD and FESEM analyses of the samples confirmed appropriate dimensions of grains with fluorite structure. Overall concentration of introduced dopants (x = 0.2) in the structure of CeO2 after the sintering process was confirmed by EDS analysis. After sintering, Raman spectroscopy confirmed retention of the oxygen vacancies in the ceria lattice, which is in accordance with the improvement of ionic conductivity of solid ionic conductors. The highest value of total conductivity was obtained for the sintered MGNP sample at 700°C (4.22 × 10−2 S cm−1), with the corresponding activation energy of 0.26 eV.
T2  - Processing and Application of Ceramics
T1  - Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs
VL  - 16
IS  - 4
SP  - 391
EP  - 401
DO  - 10.2298/PAC2204391S
ER  - 
@article{
author = "Stojmenović, Marija and Nišić, Neda and Žunić, Milan and Basoli, Francesco and Gulicovki, Jelena and Ristović, Ivica and Kragović, Milan M.",
year = "2022",
abstract = "Nanosized multi-doped ceria with composition Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-δ (CNSGDY) as perspective solid ionic conductor was obtained by modified glycine-nitrate procedure (MGNP) and room temperature self-propagating reaction (SPRT). The pressed pellets of both powders were sintered at 1550°C for 2 h in an air atmosphere. The obtained sintered samples were characterized by XRPD, Raman spectroscopy, FESEM, EDS and EIS methods. Despite a high temperature of sintering, XRPD and FESEM analyses of the samples confirmed appropriate dimensions of grains with fluorite structure. Overall concentration of introduced dopants (x = 0.2) in the structure of CeO2 after the sintering process was confirmed by EDS analysis. After sintering, Raman spectroscopy confirmed retention of the oxygen vacancies in the ceria lattice, which is in accordance with the improvement of ionic conductivity of solid ionic conductors. The highest value of total conductivity was obtained for the sintered MGNP sample at 700°C (4.22 × 10−2 S cm−1), with the corresponding activation energy of 0.26 eV.",
journal = "Processing and Application of Ceramics",
title = "Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs",
volume = "16",
number = "4",
pages = "391-401",
doi = "10.2298/PAC2204391S"
}
Stojmenović, M., Nišić, N., Žunić, M., Basoli, F., Gulicovki, J., Ristović, I.,& Kragović, M. M.. (2022). Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs. in Processing and Application of Ceramics, 16(4), 391-401.
https://doi.org/10.2298/PAC2204391S
Stojmenović M, Nišić N, Žunić M, Basoli F, Gulicovki J, Ristović I, Kragović MM. Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs. in Processing and Application of Ceramics. 2022;16(4):391-401.
doi:10.2298/PAC2204391S .
Stojmenović, Marija, Nišić, Neda, Žunić, Milan, Basoli, Francesco, Gulicovki, Jelena, Ristović, Ivica, Kragović, Milan M., "Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs" in Processing and Application of Ceramics, 16, no. 4 (2022):391-401,
https://doi.org/10.2298/PAC2204391S . .
1
1

Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC

Nišić, Neda; Gulicovski, Jelena J.; Kragović, Milan; Nedeljković, Andrijana; Žunić, Milan; Rosić, Milena; Stojmenović, Marija

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Nišić, Neda
AU  - Gulicovski, Jelena J.
AU  - Kragović, Milan
AU  - Nedeljković, Andrijana
AU  - Žunić, Milan
AU  - Rosić, Milena
AU  - Stojmenović, Marija
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10798
AB  - In the present paper, possible application of novel concept synthesis method of glass-ceramic sealant with implementation of alumosilicate-based waste material in intermediate temperature solid oxide fuel cells (IT-SOFC) was investigated. Besides basic components for glass-ceramic sealant (sample GC0), for this purpose four additional sealant compositions with certain waste content, designated as GC1, GC2, GC3, GC4, were prepared for a comparative study. Waste was added in the basic sealant composition in such a way that certain percent of alumosilicate clay was substituted with alumosilicate-based waste material, with proper amount of water as a solvent. Waste share in compositions was 5, 10, 15 and 20% of total amout of alumosilicate clay as a replacement, respectively.A total of five different joint specimens were assembled by placing a sealant paste of 10mm thickness between two bricks to form brick/glass–ceramic/brick sandwich specimens appropriate for further heat treatments. Such formed ‘green’ joints were initially air-dried for 24h at room temperature, which was required for solvent to evaporate and cause initial bonding. Heating cycle in the period of four weeks was carried out in a chamber furnace. First day samples were heated to 200 ̊C for 2 h. Each day heating temperature was raised for 100 °C while dwelling time was prolonged for one hour, so by the end of the first week samples were heated to 600 °C for 6 hours. Next three weeks annealing of the samples was performed at 600 °C for 6 hours, 700 °C for 7 hours and 800 °C for 8 h, respectively, after what the thermal cycle was completed. The heating rate of the furnace at each heating step in the given joining process was 5 °C/min,while cooling was at natural speed. Mentioned firing temperatures were selected in accordance to common operating temperature range of IT-SOFC so as to simulate real working conditions. After the completion of the cycle, it was observed that all variants of the sealant withstood high temperatures without significant cracks or damage. Moreover, after detailed chemical, physical, mechanical and optical properties examination it was determined that compositions remained unaltered, which clearly indicates to their stability and reliability that is required for their application as sealants for IT-SOFC components. In addition, this research shows the possibility of forming a cost-effective, environmentally-friendly and high- efficient sealant for application in IT-SOFC by incorporating waste materials in its composition, without significant negative effects on its performance and main properties.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade
T1  - Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC
SP  - 65
EP  - 66
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10798
ER  - 
@conference{
author = "Nišić, Neda and Gulicovski, Jelena J. and Kragović, Milan and Nedeljković, Andrijana and Žunić, Milan and Rosić, Milena and Stojmenović, Marija",
year = "2021",
abstract = "In the present paper, possible application of novel concept synthesis method of glass-ceramic sealant with implementation of alumosilicate-based waste material in intermediate temperature solid oxide fuel cells (IT-SOFC) was investigated. Besides basic components for glass-ceramic sealant (sample GC0), for this purpose four additional sealant compositions with certain waste content, designated as GC1, GC2, GC3, GC4, were prepared for a comparative study. Waste was added in the basic sealant composition in such a way that certain percent of alumosilicate clay was substituted with alumosilicate-based waste material, with proper amount of water as a solvent. Waste share in compositions was 5, 10, 15 and 20% of total amout of alumosilicate clay as a replacement, respectively.A total of five different joint specimens were assembled by placing a sealant paste of 10mm thickness between two bricks to form brick/glass–ceramic/brick sandwich specimens appropriate for further heat treatments. Such formed ‘green’ joints were initially air-dried for 24h at room temperature, which was required for solvent to evaporate and cause initial bonding. Heating cycle in the period of four weeks was carried out in a chamber furnace. First day samples were heated to 200 ̊C for 2 h. Each day heating temperature was raised for 100 °C while dwelling time was prolonged for one hour, so by the end of the first week samples were heated to 600 °C for 6 hours. Next three weeks annealing of the samples was performed at 600 °C for 6 hours, 700 °C for 7 hours and 800 °C for 8 h, respectively, after what the thermal cycle was completed. The heating rate of the furnace at each heating step in the given joining process was 5 °C/min,while cooling was at natural speed. Mentioned firing temperatures were selected in accordance to common operating temperature range of IT-SOFC so as to simulate real working conditions. After the completion of the cycle, it was observed that all variants of the sealant withstood high temperatures without significant cracks or damage. Moreover, after detailed chemical, physical, mechanical and optical properties examination it was determined that compositions remained unaltered, which clearly indicates to their stability and reliability that is required for their application as sealants for IT-SOFC components. In addition, this research shows the possibility of forming a cost-effective, environmentally-friendly and high- efficient sealant for application in IT-SOFC by incorporating waste materials in its composition, without significant negative effects on its performance and main properties.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade",
title = "Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC",
pages = "65-66",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10798"
}
Nišić, N., Gulicovski, J. J., Kragović, M., Nedeljković, A., Žunić, M., Rosić, M.,& Stojmenović, M.. (2021). Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC. in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade
Belgrade : Serbian Ceramic Society., 65-66.
https://hdl.handle.net/21.15107/rcub_vinar_10798
Nišić N, Gulicovski JJ, Kragović M, Nedeljković A, Žunić M, Rosić M, Stojmenović M. Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC. in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade. 2021;:65-66.
https://hdl.handle.net/21.15107/rcub_vinar_10798 .
Nišić, Neda, Gulicovski, Jelena J., Kragović, Milan, Nedeljković, Andrijana, Žunić, Milan, Rosić, Milena, Stojmenović, Marija, "Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC" in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade (2021):65-66,
https://hdl.handle.net/21.15107/rcub_vinar_10798 .

Potential use of slag generated from lignite combustion in hitting plants

Nišić, Neda; Kandić, Irina; Ristić, N.; Stojmenović, Marija; Gulicovski, Jelena; Kragović, Milan; Nedeljković, Andrijana

(Society of Physical Chemists of Serbia : Belgrade, 2021)

TY  - CONF
AU  - Nišić, Neda
AU  - Kandić, Irina
AU  - Ristić, N.
AU  - Stojmenović, Marija
AU  - Gulicovski, Jelena
AU  - Kragović, Milan
AU  - Nedeljković, Andrijana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11956
AB  - This paper presents the examination of potential application of slag, obtained from lignite combustion process in heating plant in Valjevo, Serbia, as a replacement for cement in mortars and concrete production. Waste slag was characterized with X-Ray Diffraction Analysis, Field Emission Scanning Electron Microscopy and Gamma spectrometric analysis, while its application possibility was investigated with testing Pozzolan activity Strength activity index, Activity index and Water requirement. The aim of this study is to determine under what conditions the slag could successfully replace cement in construction industry in certain percentages. Based on presented results it was concluded that, after mixing with silicate fume, waste slag can be used for the purpose mentioned. Optimal proportion of cement replacement is 20%-: 18% of slag and 2% of silica fume.
PB  - Society of Physical Chemists of Serbia : Belgrade
C3  - PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry
T1  - Potential use of slag generated from lignite combustion in hitting plants
SP  - 576
EP  - 579
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11956
ER  - 
@conference{
author = "Nišić, Neda and Kandić, Irina and Ristić, N. and Stojmenović, Marija and Gulicovski, Jelena and Kragović, Milan and Nedeljković, Andrijana",
year = "2021",
abstract = "This paper presents the examination of potential application of slag, obtained from lignite combustion process in heating plant in Valjevo, Serbia, as a replacement for cement in mortars and concrete production. Waste slag was characterized with X-Ray Diffraction Analysis, Field Emission Scanning Electron Microscopy and Gamma spectrometric analysis, while its application possibility was investigated with testing Pozzolan activity Strength activity index, Activity index and Water requirement. The aim of this study is to determine under what conditions the slag could successfully replace cement in construction industry in certain percentages. Based on presented results it was concluded that, after mixing with silicate fume, waste slag can be used for the purpose mentioned. Optimal proportion of cement replacement is 20%-: 18% of slag and 2% of silica fume.",
publisher = "Society of Physical Chemists of Serbia : Belgrade",
journal = "PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry",
title = "Potential use of slag generated from lignite combustion in hitting plants",
pages = "576-579",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11956"
}
Nišić, N., Kandić, I., Ristić, N., Stojmenović, M., Gulicovski, J., Kragović, M.,& Nedeljković, A.. (2021). Potential use of slag generated from lignite combustion in hitting plants. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry
Society of Physical Chemists of Serbia : Belgrade., 576-579.
https://hdl.handle.net/21.15107/rcub_vinar_11956
Nišić N, Kandić I, Ristić N, Stojmenović M, Gulicovski J, Kragović M, Nedeljković A. Potential use of slag generated from lignite combustion in hitting plants. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry. 2021;:576-579.
https://hdl.handle.net/21.15107/rcub_vinar_11956 .
Nišić, Neda, Kandić, Irina, Ristić, N., Stojmenović, Marija, Gulicovski, Jelena, Kragović, Milan, Nedeljković, Andrijana, "Potential use of slag generated from lignite combustion in hitting plants" in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry (2021):576-579,
https://hdl.handle.net/21.15107/rcub_vinar_11956 .

Influence of the modification on the point of zero charge of the waste slag generated by lignite combustion in heating plants and its properties for xanthates removal from aqueous solutions

Nedeljković, Andrijana; Nišić, Neda; Stojmenović, Marija; Gulicovski, Jelena; Ristović, Ivica; Jović, Aleksandar; Kragović, Milan

(Belgrade : University of Belgrade : Faculty of Mining and Geology, 2021)

TY  - CONF
AU  - Nedeljković, Andrijana
AU  - Nišić, Neda
AU  - Stojmenović, Marija
AU  - Gulicovski, Jelena
AU  - Ristović, Ivica
AU  - Jović, Aleksandar
AU  - Kragović, Milan
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11975
AB  - In presented paper influence of the modification on the point of zero charge of the waste slag generated by lignite combustion in heating plants and its properties for xanthates removal from aqueous solutions were investigated. The obtained results showed that the modification did have negligible effect on the point of zero charge and after modification the pHpzc changed from 6.92 to 6.90. The preliminary test of the xanthates removal from aqueous solutions showed that modification significantly increased removal efficiency, from 18.50 to 98.60 %.
PB  - Belgrade : University of Belgrade : Faculty of Mining and Geology
C3  - MEP-21 : 8th International Conference Mining and Environmental Protection : Proceedings book
T1  - Influence of the modification on the point of zero charge of the waste slag generated by lignite combustion in heating plants and its properties for xanthates removal from aqueous solutions
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11975
ER  - 
@conference{
author = "Nedeljković, Andrijana and Nišić, Neda and Stojmenović, Marija and Gulicovski, Jelena and Ristović, Ivica and Jović, Aleksandar and Kragović, Milan",
year = "2021",
abstract = "In presented paper influence of the modification on the point of zero charge of the waste slag generated by lignite combustion in heating plants and its properties for xanthates removal from aqueous solutions were investigated. The obtained results showed that the modification did have negligible effect on the point of zero charge and after modification the pHpzc changed from 6.92 to 6.90. The preliminary test of the xanthates removal from aqueous solutions showed that modification significantly increased removal efficiency, from 18.50 to 98.60 %.",
publisher = "Belgrade : University of Belgrade : Faculty of Mining and Geology",
journal = "MEP-21 : 8th International Conference Mining and Environmental Protection : Proceedings book",
title = "Influence of the modification on the point of zero charge of the waste slag generated by lignite combustion in heating plants and its properties for xanthates removal from aqueous solutions",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11975"
}
Nedeljković, A., Nišić, N., Stojmenović, M., Gulicovski, J., Ristović, I., Jović, A.,& Kragović, M.. (2021). Influence of the modification on the point of zero charge of the waste slag generated by lignite combustion in heating plants and its properties for xanthates removal from aqueous solutions. in MEP-21 : 8th International Conference Mining and Environmental Protection : Proceedings book
Belgrade : University of Belgrade : Faculty of Mining and Geology..
https://hdl.handle.net/21.15107/rcub_vinar_11975
Nedeljković A, Nišić N, Stojmenović M, Gulicovski J, Ristović I, Jović A, Kragović M. Influence of the modification on the point of zero charge of the waste slag generated by lignite combustion in heating plants and its properties for xanthates removal from aqueous solutions. in MEP-21 : 8th International Conference Mining and Environmental Protection : Proceedings book. 2021;.
https://hdl.handle.net/21.15107/rcub_vinar_11975 .
Nedeljković, Andrijana, Nišić, Neda, Stojmenović, Marija, Gulicovski, Jelena, Ristović, Ivica, Jović, Aleksandar, Kragović, Milan, "Influence of the modification on the point of zero charge of the waste slag generated by lignite combustion in heating plants and its properties for xanthates removal from aqueous solutions" in MEP-21 : 8th International Conference Mining and Environmental Protection : Proceedings book (2021),
https://hdl.handle.net/21.15107/rcub_vinar_11975 .