Nikolic, RM

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Thermodynamics of lead(II) halide complex formation in calcium nitrate tetrahydrate - Acetamide melts

Gadžurić, Slobodan; Zsigrai, Istvan J.; Nikolic, RM

(2001)

TY  - JOUR
AU  - Gadžurić, Slobodan
AU  - Zsigrai, Istvan J.
AU  - Nikolic, RM
PY  - 2001
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2498
AB  - The complex formation between lead(II) ions and chloride and bromide ions in melts of Ca(NO3)(2 .) 4H(2)O . aCH(3)CONH(2) has been studied at different temperatures between 30 and 70 C. The formation constants of the complexes PbX+ and PbX2 (X = Cl, Br) were determined from emf measurements by means of Ag/AgX electrodes. The dependence of the formation constants for PbCl+ on the solvent melt composition has been analysed. The thermodynamic parameters DeltaH(11)(0) and DeltaS(11)(0) for PbX+ complex formation have been estimated. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated and anhydrous salt melts.
T2  - Zeitschrift fur Naturforschung. Section A: Journal of Physical Sciences
T1  - Thermodynamics of lead(II) halide complex formation in calcium nitrate tetrahydrate - Acetamide melts
VL  - 56
IS  - 12
SP  - 832
EP  - 836
UR  - https://hdl.handle.net/21.15107/rcub_vinar_2498
ER  - 
@article{
author = "Gadžurić, Slobodan and Zsigrai, Istvan J. and Nikolic, RM",
year = "2001",
abstract = "The complex formation between lead(II) ions and chloride and bromide ions in melts of Ca(NO3)(2 .) 4H(2)O . aCH(3)CONH(2) has been studied at different temperatures between 30 and 70 C. The formation constants of the complexes PbX+ and PbX2 (X = Cl, Br) were determined from emf measurements by means of Ag/AgX electrodes. The dependence of the formation constants for PbCl+ on the solvent melt composition has been analysed. The thermodynamic parameters DeltaH(11)(0) and DeltaS(11)(0) for PbX+ complex formation have been estimated. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated and anhydrous salt melts.",
journal = "Zeitschrift fur Naturforschung. Section A: Journal of Physical Sciences",
title = "Thermodynamics of lead(II) halide complex formation in calcium nitrate tetrahydrate - Acetamide melts",
volume = "56",
number = "12",
pages = "832-836",
url = "https://hdl.handle.net/21.15107/rcub_vinar_2498"
}
Gadžurić, S., Zsigrai, I. J.,& Nikolic, R.. (2001). Thermodynamics of lead(II) halide complex formation in calcium nitrate tetrahydrate - Acetamide melts. in Zeitschrift fur Naturforschung. Section A: Journal of Physical Sciences, 56(12), 832-836.
https://hdl.handle.net/21.15107/rcub_vinar_2498
Gadžurić S, Zsigrai IJ, Nikolic R. Thermodynamics of lead(II) halide complex formation in calcium nitrate tetrahydrate - Acetamide melts. in Zeitschrift fur Naturforschung. Section A: Journal of Physical Sciences. 2001;56(12):832-836.
https://hdl.handle.net/21.15107/rcub_vinar_2498 .
Gadžurić, Slobodan, Zsigrai, Istvan J., Nikolic, RM, "Thermodynamics of lead(II) halide complex formation in calcium nitrate tetrahydrate - Acetamide melts" in Zeitschrift fur Naturforschung. Section A: Journal of Physical Sciences, 56, no. 12 (2001):832-836,
https://hdl.handle.net/21.15107/rcub_vinar_2498 .
2

Thermodynamics of cadmium halide complex formation in acetamide-calcium nitrate tetrahydrate melt

Zsigrai, Istvan J.; Gadžurić, Slobodan; Nikolic, RM

(2001)

TY  - JOUR
AU  - Zsigrai, Istvan J.
AU  - Gadžurić, Slobodan
AU  - Nikolic, RM
PY  - 2001
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2412
AB  - The complex formation between cadmium(II) ions and chloride and bromide ions in the melt of 0.8CH(3)CONH(2)-0.2Ca(NO3)(2). 4H(2)O has been studied at six temperatures between 30 and 80 degreesC. The formation constants of the complexes CdX+ and CdX2 (X=CI, Br) were determined from Emf measurements by means of Ag/AgX electrodes. The thermodynamic parameters DeltaH(mn)degrees and DeltaS(mn)degrees for the stepwise complex formation [GRAPHICS] have been estimated. The results are DeltaH(11)degrees = 4.2 kJ mol(-1). DeltaS(11)degrees = 52.4 J K-1 mol(-1), DeltaH(12)degrees = 3.3 kJ mol(-1) DeltaS(12)degrees = 40.7 J K-1 mol(-1) for the chloride complexes and DeltaH(11)degrees = -3.3 kJ mol(-1), DeltaS(11)degrees = 33.0 J K-1 mol(-1), DeltaH(12)degrees = -2.5 kJ mol(-1), DeltaS(12)degrees = 30.4 J K-1 mol(-1) for the bromide complexes. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated salt melts.
T2  - Magyar Kemiai Folyoirat
T1  - Thermodynamics of cadmium halide complex formation in acetamide-calcium nitrate tetrahydrate melt
VL  - 107
IS  - 1
SP  - 36
EP  - 42
UR  - https://hdl.handle.net/21.15107/rcub_vinar_2412
ER  - 
@article{
author = "Zsigrai, Istvan J. and Gadžurić, Slobodan and Nikolic, RM",
year = "2001",
abstract = "The complex formation between cadmium(II) ions and chloride and bromide ions in the melt of 0.8CH(3)CONH(2)-0.2Ca(NO3)(2). 4H(2)O has been studied at six temperatures between 30 and 80 degreesC. The formation constants of the complexes CdX+ and CdX2 (X=CI, Br) were determined from Emf measurements by means of Ag/AgX electrodes. The thermodynamic parameters DeltaH(mn)degrees and DeltaS(mn)degrees for the stepwise complex formation [GRAPHICS] have been estimated. The results are DeltaH(11)degrees = 4.2 kJ mol(-1). DeltaS(11)degrees = 52.4 J K-1 mol(-1), DeltaH(12)degrees = 3.3 kJ mol(-1) DeltaS(12)degrees = 40.7 J K-1 mol(-1) for the chloride complexes and DeltaH(11)degrees = -3.3 kJ mol(-1), DeltaS(11)degrees = 33.0 J K-1 mol(-1), DeltaH(12)degrees = -2.5 kJ mol(-1), DeltaS(12)degrees = 30.4 J K-1 mol(-1) for the bromide complexes. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated salt melts.",
journal = "Magyar Kemiai Folyoirat",
title = "Thermodynamics of cadmium halide complex formation in acetamide-calcium nitrate tetrahydrate melt",
volume = "107",
number = "1",
pages = "36-42",
url = "https://hdl.handle.net/21.15107/rcub_vinar_2412"
}
Zsigrai, I. J., Gadžurić, S.,& Nikolic, R.. (2001). Thermodynamics of cadmium halide complex formation in acetamide-calcium nitrate tetrahydrate melt. in Magyar Kemiai Folyoirat, 107(1), 36-42.
https://hdl.handle.net/21.15107/rcub_vinar_2412
Zsigrai IJ, Gadžurić S, Nikolic R. Thermodynamics of cadmium halide complex formation in acetamide-calcium nitrate tetrahydrate melt. in Magyar Kemiai Folyoirat. 2001;107(1):36-42.
https://hdl.handle.net/21.15107/rcub_vinar_2412 .
Zsigrai, Istvan J., Gadžurić, Slobodan, Nikolic, RM, "Thermodynamics of cadmium halide complex formation in acetamide-calcium nitrate tetrahydrate melt" in Magyar Kemiai Folyoirat, 107, no. 1 (2001):36-42,
https://hdl.handle.net/21.15107/rcub_vinar_2412 .

Thermodynamics of cadmium halide complex formation in acetamide - Calcium nitrate tetrahydrate melt

Gadžurić, Slobodan; Zsigrai, Istvan J.; Nikolic, RM

(1999)

TY  - JOUR
AU  - Gadžurić, Slobodan
AU  - Zsigrai, Istvan J.
AU  - Nikolic, RM
PY  - 1999
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2297
AB  - The complex formation between cadmium(II) ions and chloride and bromide ions in the melt of 0.8CH(3)CONH(2)-0.2Ca(NO3)(2). 4H(2)O has been studied at six temperatures between 30 and 80 degrees C. The formation constants of the complexes CdX+ and CdX2 (X-Cl Br) were determined from emf measurements by means of Ag/AgX electrodes. The thermodynamic parameters Delta H(mn)degrees, and Delta S(mn)degrees, for the stepwise complex formation CdmXn-12m-n + X(-)reversible arrow CdmXn2m-n have been estimated. The results are Delta H(11)degrees = 4.2 kJ mol(-1), Delta S(11)degrees = 52.4 J K-1 mol(-1), Delta H(12)degrees = 3.3 kJ mol(-1), Delta S(12)degrees = 40.7 J K-1 mol(-1) for the chloride complexes and Delta H(11)degrees = -3.3 kJ mol(-1), Delta S(11)degrees -33.0 J K-1 mol(-1), Delta H(12)degrees = -2.5 kJ mol(-1), Delta S(12)degrees = 30.4 J K-1 mol(-1) for the bromide complexes. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated salt melts. (C) 1999 Elsevier Science B.V. All rights reserved.
T2  - Journal of Molecular Liquids
T1  - Thermodynamics of cadmium halide complex formation in acetamide - Calcium nitrate tetrahydrate melt
VL  - 83
IS  - 1-3
SP  - 75
EP  - 82
DO  - 10.1016/S0167-7322(99)00074-4
ER  - 
@article{
author = "Gadžurić, Slobodan and Zsigrai, Istvan J. and Nikolic, RM",
year = "1999",
abstract = "The complex formation between cadmium(II) ions and chloride and bromide ions in the melt of 0.8CH(3)CONH(2)-0.2Ca(NO3)(2). 4H(2)O has been studied at six temperatures between 30 and 80 degrees C. The formation constants of the complexes CdX+ and CdX2 (X-Cl Br) were determined from emf measurements by means of Ag/AgX electrodes. The thermodynamic parameters Delta H(mn)degrees, and Delta S(mn)degrees, for the stepwise complex formation CdmXn-12m-n + X(-)reversible arrow CdmXn2m-n have been estimated. The results are Delta H(11)degrees = 4.2 kJ mol(-1), Delta S(11)degrees = 52.4 J K-1 mol(-1), Delta H(12)degrees = 3.3 kJ mol(-1), Delta S(12)degrees = 40.7 J K-1 mol(-1) for the chloride complexes and Delta H(11)degrees = -3.3 kJ mol(-1), Delta S(11)degrees -33.0 J K-1 mol(-1), Delta H(12)degrees = -2.5 kJ mol(-1), Delta S(12)degrees = 30.4 J K-1 mol(-1) for the bromide complexes. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated salt melts. (C) 1999 Elsevier Science B.V. All rights reserved.",
journal = "Journal of Molecular Liquids",
title = "Thermodynamics of cadmium halide complex formation in acetamide - Calcium nitrate tetrahydrate melt",
volume = "83",
number = "1-3",
pages = "75-82",
doi = "10.1016/S0167-7322(99)00074-4"
}
Gadžurić, S., Zsigrai, I. J.,& Nikolic, R.. (1999). Thermodynamics of cadmium halide complex formation in acetamide - Calcium nitrate tetrahydrate melt. in Journal of Molecular Liquids, 83(1-3), 75-82.
https://doi.org/10.1016/S0167-7322(99)00074-4
Gadžurić S, Zsigrai IJ, Nikolic R. Thermodynamics of cadmium halide complex formation in acetamide - Calcium nitrate tetrahydrate melt. in Journal of Molecular Liquids. 1999;83(1-3):75-82.
doi:10.1016/S0167-7322(99)00074-4 .
Gadžurić, Slobodan, Zsigrai, Istvan J., Nikolic, RM, "Thermodynamics of cadmium halide complex formation in acetamide - Calcium nitrate tetrahydrate melt" in Journal of Molecular Liquids, 83, no. 1-3 (1999):75-82,
https://doi.org/10.1016/S0167-7322(99)00074-4 . .
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