Direct Formation of Burkeite in the Geothermal Waters at Vranjska Banja, Serbia
Само за регистроване кориснике
2019
Аутори
Todorović, Bratislav Ž.Stojiljković, Dragan T.
Pantić-Petrović, Tanja
Matović, Branko
Prekajski-Đorđević, Marija D.
Petrović, Sanja M.
Stojiljković, Milena S.
Stevanović, Miloš M.
Чланак у часопису (Објављена верзија)
,
© 2019, International Association for Mathematical Geosciences
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There are no available data about direct burkeite formation on the geothermal waters pipelines in Europe. Data about accompanying minerals of burkeite are also scarce. This mineral has been found in the scale on pipelines of VG-2 and VG-3 boreholes at Vranjska Banja, Serbia. Geothermal waters from these boreholes have temperatures in the range of 103 and 105 °C which classifies them to the warmest waters in the continental Europe. Based on physicochemical and geochemical data, VG-2 and VG-3 geothermal waters can be classified as Na–Alk–SO4Cl type of waters. According to their temperatures, total hardness and pH values, these waters belong to hyperthermal, very soft and moderately alkaline. Calculated LSI (0.4 and 1.7) and RSI (6.5 and 4.8) values indicate their scale formation tendency. Results of the spectrometric scale examination from the pipe deposits provide a clear qualitative and quantitative burkeite characterization with its accompanying minerals. FTIR analysis points to the p...resence of carbonate (1766, 1458, 877 and 705 cm−1) and sulfate bands (1139, 1116 and 617 cm−1). Apart from the qualitative analysis, XRD also shows the burkeite mass part in the scale. VG-2 geothermal water contains about 50% of burkeite, which is associated with trona mineral (40%) and smaller amount of halite of about 10%. Burkeite is a dominant phase (> 60%) in VG-3 water, with the presence of a significant halite quantity (> 35%) and a minor calcite quantity (2%). © 2019, International Association for Mathematical Geosciences.
Кључне речи:
Burkeite / Geothermal water / Scaling / Vranjska BanjaИзвор:
Natural Resources Research, 2019, 28, 4, 1259-1267Финансирање / пројекти:
- Могућности коришћења потенцијала геотермалних вода у Јабланичком и Пчињском округу (RS-MESTD-Technological Development (TD or TR)-33034)
- Синтеза, процесирање и карактеризација наноструктурних материјала за примену у области енергије, механичког инжењерства, заштите животне стредине и биомедицине (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45012)
DOI: 10.1007/s11053-019-09455-y
ISSN: 1520-7439
WoS: 000485321200003
Scopus: 2-s2.0-85060248491
Колекције
Институција/група
VinčaTY - JOUR AU - Todorović, Bratislav Ž. AU - Stojiljković, Dragan T. AU - Pantić-Petrović, Tanja AU - Matović, Branko AU - Prekajski-Đorđević, Marija D. AU - Petrović, Sanja M. AU - Stojiljković, Milena S. AU - Stevanović, Miloš M. PY - 2019 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8493 AB - There are no available data about direct burkeite formation on the geothermal waters pipelines in Europe. Data about accompanying minerals of burkeite are also scarce. This mineral has been found in the scale on pipelines of VG-2 and VG-3 boreholes at Vranjska Banja, Serbia. Geothermal waters from these boreholes have temperatures in the range of 103 and 105 °C which classifies them to the warmest waters in the continental Europe. Based on physicochemical and geochemical data, VG-2 and VG-3 geothermal waters can be classified as Na–Alk–SO4Cl type of waters. According to their temperatures, total hardness and pH values, these waters belong to hyperthermal, very soft and moderately alkaline. Calculated LSI (0.4 and 1.7) and RSI (6.5 and 4.8) values indicate their scale formation tendency. Results of the spectrometric scale examination from the pipe deposits provide a clear qualitative and quantitative burkeite characterization with its accompanying minerals. FTIR analysis points to the presence of carbonate (1766, 1458, 877 and 705 cm−1) and sulfate bands (1139, 1116 and 617 cm−1). Apart from the qualitative analysis, XRD also shows the burkeite mass part in the scale. VG-2 geothermal water contains about 50% of burkeite, which is associated with trona mineral (40%) and smaller amount of halite of about 10%. Burkeite is a dominant phase (> 60%) in VG-3 water, with the presence of a significant halite quantity (> 35%) and a minor calcite quantity (2%). © 2019, International Association for Mathematical Geosciences. T2 - Natural Resources Research T1 - Direct Formation of Burkeite in the Geothermal Waters at Vranjska Banja, Serbia VL - 28 IS - 4 SP - 1259 EP - 1267 DO - 10.1007/s11053-019-09455-y ER -
@article{ author = "Todorović, Bratislav Ž. and Stojiljković, Dragan T. and Pantić-Petrović, Tanja and Matović, Branko and Prekajski-Đorđević, Marija D. and Petrović, Sanja M. and Stojiljković, Milena S. and Stevanović, Miloš M.", year = "2019", abstract = "There are no available data about direct burkeite formation on the geothermal waters pipelines in Europe. Data about accompanying minerals of burkeite are also scarce. This mineral has been found in the scale on pipelines of VG-2 and VG-3 boreholes at Vranjska Banja, Serbia. Geothermal waters from these boreholes have temperatures in the range of 103 and 105 °C which classifies them to the warmest waters in the continental Europe. Based on physicochemical and geochemical data, VG-2 and VG-3 geothermal waters can be classified as Na–Alk–SO4Cl type of waters. According to their temperatures, total hardness and pH values, these waters belong to hyperthermal, very soft and moderately alkaline. Calculated LSI (0.4 and 1.7) and RSI (6.5 and 4.8) values indicate their scale formation tendency. Results of the spectrometric scale examination from the pipe deposits provide a clear qualitative and quantitative burkeite characterization with its accompanying minerals. FTIR analysis points to the presence of carbonate (1766, 1458, 877 and 705 cm−1) and sulfate bands (1139, 1116 and 617 cm−1). Apart from the qualitative analysis, XRD also shows the burkeite mass part in the scale. VG-2 geothermal water contains about 50% of burkeite, which is associated with trona mineral (40%) and smaller amount of halite of about 10%. Burkeite is a dominant phase (> 60%) in VG-3 water, with the presence of a significant halite quantity (> 35%) and a minor calcite quantity (2%). © 2019, International Association for Mathematical Geosciences.", journal = "Natural Resources Research", title = "Direct Formation of Burkeite in the Geothermal Waters at Vranjska Banja, Serbia", volume = "28", number = "4", pages = "1259-1267", doi = "10.1007/s11053-019-09455-y" }
Todorović, B. Ž., Stojiljković, D. T., Pantić-Petrović, T., Matović, B., Prekajski-Đorđević, M. D., Petrović, S. M., Stojiljković, M. S.,& Stevanović, M. M.. (2019). Direct Formation of Burkeite in the Geothermal Waters at Vranjska Banja, Serbia. in Natural Resources Research, 28(4), 1259-1267. https://doi.org/10.1007/s11053-019-09455-y
Todorović BŽ, Stojiljković DT, Pantić-Petrović T, Matović B, Prekajski-Đorđević MD, Petrović SM, Stojiljković MS, Stevanović MM. Direct Formation of Burkeite in the Geothermal Waters at Vranjska Banja, Serbia. in Natural Resources Research. 2019;28(4):1259-1267. doi:10.1007/s11053-019-09455-y .
Todorović, Bratislav Ž., Stojiljković, Dragan T., Pantić-Petrović, Tanja, Matović, Branko, Prekajski-Đorđević, Marija D., Petrović, Sanja M., Stojiljković, Milena S., Stevanović, Miloš M., "Direct Formation of Burkeite in the Geothermal Waters at Vranjska Banja, Serbia" in Natural Resources Research, 28, no. 4 (2019):1259-1267, https://doi.org/10.1007/s11053-019-09455-y . .