Influence of sulphide precursor on crystal phase of ternary I-III-VI2 semiconductors
Нема приказа
Аутори
Beloš, Milica V.Abazović, Nadica
Kuljanin-Jakovljević, Jadranka Ž.
Janković, Ivana A.
Ahrenkiel, Scott Phillip
Mitrić, Miodrag
Čomor, Mirjana
Чланак у часопису
Метаподаци
Приказ свих података о документуАпстракт
Samples of AgInS2 and CuInS2 nanoparticles were synthesized by hot-injection method at 270 degrees C using 1-dodecanethiol (DT) and elemental sulphur (S) as sulphide precursors, and oleylamine as reaction medium and surfactant. Composition, crystal structure, and particle size of obtained materials were tracked by XRD and TEM/HRTEM measurements. It was shown that, due to its dual role as sulphur source and surfactant, DT drastically slows formation of desired material. Samples obtained with DT even after 4 h of reaction have traces of intermediary compound (beta-In2S3), whereas in samples synthesized with elemental S these traces are less pronounced. The growth mechanism and influence of each reaction step are discussed in detail.
Кључне речи:
Ternary chalcogenides / I-III-VI2 semiconductors / Crystal phase / Hot-injection synthesis / X-ray diffraction / HRTEM / ElectronicsИзвор:
Journal of Nanoparticle Research, 2013, 15, 12Финансирање / пројекти:
- Материјали редуковане димензионалности за ефикасну апсорпцију светлости и конверзију енергије (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45020)
- Утицај величине, облика и структуре наночестица на њихова својства и својства нанокомпозита (RS-MESTD-Basic Research (BR or ON)-172056)
- COST Actions [CM1101, MP1106]
DOI: 10.1007/s11051-013-2148-6
ISSN: 1388-0764; 1572-896X
WoS: 000327527200001
Scopus: 2-s2.0-84888248121
Колекције
Институција/група
VinčaTY - JOUR AU - Beloš, Milica V. AU - Abazović, Nadica AU - Kuljanin-Jakovljević, Jadranka Ž. AU - Janković, Ivana A. AU - Ahrenkiel, Scott Phillip AU - Mitrić, Miodrag AU - Čomor, Mirjana PY - 2013 UR - https://vinar.vin.bg.ac.rs/handle/123456789/5767 AB - Samples of AgInS2 and CuInS2 nanoparticles were synthesized by hot-injection method at 270 degrees C using 1-dodecanethiol (DT) and elemental sulphur (S) as sulphide precursors, and oleylamine as reaction medium and surfactant. Composition, crystal structure, and particle size of obtained materials were tracked by XRD and TEM/HRTEM measurements. It was shown that, due to its dual role as sulphur source and surfactant, DT drastically slows formation of desired material. Samples obtained with DT even after 4 h of reaction have traces of intermediary compound (beta-In2S3), whereas in samples synthesized with elemental S these traces are less pronounced. The growth mechanism and influence of each reaction step are discussed in detail. T2 - Journal of Nanoparticle Research T1 - Influence of sulphide precursor on crystal phase of ternary I-III-VI2 semiconductors VL - 15 IS - 12 DO - 10.1007/s11051-013-2148-6 ER -
@article{ author = "Beloš, Milica V. and Abazović, Nadica and Kuljanin-Jakovljević, Jadranka Ž. and Janković, Ivana A. and Ahrenkiel, Scott Phillip and Mitrić, Miodrag and Čomor, Mirjana", year = "2013", abstract = "Samples of AgInS2 and CuInS2 nanoparticles were synthesized by hot-injection method at 270 degrees C using 1-dodecanethiol (DT) and elemental sulphur (S) as sulphide precursors, and oleylamine as reaction medium and surfactant. Composition, crystal structure, and particle size of obtained materials were tracked by XRD and TEM/HRTEM measurements. It was shown that, due to its dual role as sulphur source and surfactant, DT drastically slows formation of desired material. Samples obtained with DT even after 4 h of reaction have traces of intermediary compound (beta-In2S3), whereas in samples synthesized with elemental S these traces are less pronounced. The growth mechanism and influence of each reaction step are discussed in detail.", journal = "Journal of Nanoparticle Research", title = "Influence of sulphide precursor on crystal phase of ternary I-III-VI2 semiconductors", volume = "15", number = "12", doi = "10.1007/s11051-013-2148-6" }
Beloš, M. V., Abazović, N., Kuljanin-Jakovljević, J. Ž., Janković, I. A., Ahrenkiel, S. P., Mitrić, M.,& Čomor, M.. (2013). Influence of sulphide precursor on crystal phase of ternary I-III-VI2 semiconductors. in Journal of Nanoparticle Research, 15(12). https://doi.org/10.1007/s11051-013-2148-6
Beloš MV, Abazović N, Kuljanin-Jakovljević JŽ, Janković IA, Ahrenkiel SP, Mitrić M, Čomor M. Influence of sulphide precursor on crystal phase of ternary I-III-VI2 semiconductors. in Journal of Nanoparticle Research. 2013;15(12). doi:10.1007/s11051-013-2148-6 .
Beloš, Milica V., Abazović, Nadica, Kuljanin-Jakovljević, Jadranka Ž., Janković, Ivana A., Ahrenkiel, Scott Phillip, Mitrić, Miodrag, Čomor, Mirjana, "Influence of sulphide precursor on crystal phase of ternary I-III-VI2 semiconductors" in Journal of Nanoparticle Research, 15, no. 12 (2013), https://doi.org/10.1007/s11051-013-2148-6 . .