Transition metal complexes with thiosemicarbazide-based ligands. XLIV. Aqua(3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde 3-methylisothiosemicarbazone-kappa O-3,N-1,N-4)nitratocopper(II)nitrate
Апстракт
The title complex, [Cu(NO3)(C10H14N4O2S)(H2O)](NO3), is the first metal complex with a Schiff base derived from isothiosemicarbazide and pyridoxal (pyridoxal is 3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde). The Cu-II environment is a square pyramid, the equatorial plane of which is formed by the tridentate ONN-coordinated isothiosemicarbazone and one water molecule, while the nitrate ligand is in the apical position. The existence of numerous strong intermolecular hydrogen bonds, and weak C-H...O and C-H...pi interactions, leads to a three-dimensional supramolecular structure.
Извор:
Acta Crystallographica. Section C: Crystal Structure Communications, 2002, 58, M514-M516
DOI: 10.1107/S010827010201586X
ISSN: 0108-2701
PubMed: 12359931
WoS: 000178399800014
Scopus: 2-s2.0-0036804825
Колекције
Институција/група
VinčaTY - JOUR AU - Leovac, Vukadin M. AU - Jevtović, V. S AU - Bogdanović, Goran A. PY - 2002 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2552 AB - The title complex, [Cu(NO3)(C10H14N4O2S)(H2O)](NO3), is the first metal complex with a Schiff base derived from isothiosemicarbazide and pyridoxal (pyridoxal is 3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde). The Cu-II environment is a square pyramid, the equatorial plane of which is formed by the tridentate ONN-coordinated isothiosemicarbazone and one water molecule, while the nitrate ligand is in the apical position. The existence of numerous strong intermolecular hydrogen bonds, and weak C-H...O and C-H...pi interactions, leads to a three-dimensional supramolecular structure. T2 - Acta Crystallographica. Section C: Crystal Structure Communications T1 - Transition metal complexes with thiosemicarbazide-based ligands. XLIV. Aqua(3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde 3-methylisothiosemicarbazone-kappa O-3,N-1,N-4)nitratocopper(II)nitrate VL - 58 SP - M514 EP - M516 DO - 10.1107/S010827010201586X ER -
@article{ author = "Leovac, Vukadin M. and Jevtović, V. S and Bogdanović, Goran A.", year = "2002", abstract = "The title complex, [Cu(NO3)(C10H14N4O2S)(H2O)](NO3), is the first metal complex with a Schiff base derived from isothiosemicarbazide and pyridoxal (pyridoxal is 3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde). The Cu-II environment is a square pyramid, the equatorial plane of which is formed by the tridentate ONN-coordinated isothiosemicarbazone and one water molecule, while the nitrate ligand is in the apical position. The existence of numerous strong intermolecular hydrogen bonds, and weak C-H...O and C-H...pi interactions, leads to a three-dimensional supramolecular structure.", journal = "Acta Crystallographica. Section C: Crystal Structure Communications", title = "Transition metal complexes with thiosemicarbazide-based ligands. XLIV. Aqua(3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde 3-methylisothiosemicarbazone-kappa O-3,N-1,N-4)nitratocopper(II)nitrate", volume = "58", pages = "M514-M516", doi = "10.1107/S010827010201586X" }
Leovac, V. M., Jevtović, V. S.,& Bogdanović, G. A.. (2002). Transition metal complexes with thiosemicarbazide-based ligands. XLIV. Aqua(3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde 3-methylisothiosemicarbazone-kappa O-3,N-1,N-4)nitratocopper(II)nitrate. in Acta Crystallographica. Section C: Crystal Structure Communications, 58, M514-M516. https://doi.org/10.1107/S010827010201586X
Leovac VM, Jevtović VS, Bogdanović GA. Transition metal complexes with thiosemicarbazide-based ligands. XLIV. Aqua(3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde 3-methylisothiosemicarbazone-kappa O-3,N-1,N-4)nitratocopper(II)nitrate. in Acta Crystallographica. Section C: Crystal Structure Communications. 2002;58:M514-M516. doi:10.1107/S010827010201586X .
Leovac, Vukadin M., Jevtović, V. S, Bogdanović, Goran A., "Transition metal complexes with thiosemicarbazide-based ligands. XLIV. Aqua(3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde 3-methylisothiosemicarbazone-kappa O-3,N-1,N-4)nitratocopper(II)nitrate" in Acta Crystallographica. Section C: Crystal Structure Communications, 58 (2002):M514-M516, https://doi.org/10.1107/S010827010201586X . .