Microcalorimetric studies of electrolyte mixtures: HCl-GaCl3 - Application of Pitzers model
Апстракт
The heat of mixing of HCl and GaCl3 concentrated isomolal aqueous solutions has been measured, in the 0.0005-0.159 molality and 293-333 K temperature range by a flow-mix microcalorimetric method, to determine the thermodynamic properties of the solutions. The results obtained have been successfully explained by Fitters ion interaction model. Fitters mixing coefficients have been calculated and used to study the nature and intensity of ion interactions in the mixed solutions. Using Fitters parameters, the activity coefficients of the mixture components have been calculated. (C) 2000 Elsevier Science B.V. All rights reserved.
Кључне речи:
heat of mixing / microcalorimetry / electrolytes / thermodynamics of mixing / Pitzers modelИзвор:
Thermochimica Acta, 2000, 351, 1-2, 153-157
DOI: 10.1016/S0040-6031(00)00434-2
ISSN: 0040-6031
WoS: 000087255800021
Scopus: 2-s2.0-0034209389
Колекције
Институција/група
VinčaTY - JOUR AU - Marković, Mirjana AU - Milonjić, Slobodan K. PY - 2000 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2346 AB - The heat of mixing of HCl and GaCl3 concentrated isomolal aqueous solutions has been measured, in the 0.0005-0.159 molality and 293-333 K temperature range by a flow-mix microcalorimetric method, to determine the thermodynamic properties of the solutions. The results obtained have been successfully explained by Fitters ion interaction model. Fitters mixing coefficients have been calculated and used to study the nature and intensity of ion interactions in the mixed solutions. Using Fitters parameters, the activity coefficients of the mixture components have been calculated. (C) 2000 Elsevier Science B.V. All rights reserved. T2 - Thermochimica Acta T1 - Microcalorimetric studies of electrolyte mixtures: HCl-GaCl3 - Application of Pitzers model VL - 351 IS - 1-2 SP - 153 EP - 157 DO - 10.1016/S0040-6031(00)00434-2 ER -
@article{ author = "Marković, Mirjana and Milonjić, Slobodan K.", year = "2000", abstract = "The heat of mixing of HCl and GaCl3 concentrated isomolal aqueous solutions has been measured, in the 0.0005-0.159 molality and 293-333 K temperature range by a flow-mix microcalorimetric method, to determine the thermodynamic properties of the solutions. The results obtained have been successfully explained by Fitters ion interaction model. Fitters mixing coefficients have been calculated and used to study the nature and intensity of ion interactions in the mixed solutions. Using Fitters parameters, the activity coefficients of the mixture components have been calculated. (C) 2000 Elsevier Science B.V. All rights reserved.", journal = "Thermochimica Acta", title = "Microcalorimetric studies of electrolyte mixtures: HCl-GaCl3 - Application of Pitzers model", volume = "351", number = "1-2", pages = "153-157", doi = "10.1016/S0040-6031(00)00434-2" }
Marković, M.,& Milonjić, S. K.. (2000). Microcalorimetric studies of electrolyte mixtures: HCl-GaCl3 - Application of Pitzers model. in Thermochimica Acta, 351(1-2), 153-157. https://doi.org/10.1016/S0040-6031(00)00434-2
Marković M, Milonjić SK. Microcalorimetric studies of electrolyte mixtures: HCl-GaCl3 - Application of Pitzers model. in Thermochimica Acta. 2000;351(1-2):153-157. doi:10.1016/S0040-6031(00)00434-2 .
Marković, Mirjana, Milonjić, Slobodan K., "Microcalorimetric studies of electrolyte mixtures: HCl-GaCl3 - Application of Pitzers model" in Thermochimica Acta, 351, no. 1-2 (2000):153-157, https://doi.org/10.1016/S0040-6031(00)00434-2 . .